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Surface functionalization of polypropylene nonwovens by metallic deposition

机译:通过金属沉积对聚丙烯无纺布进行表面功能化

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In this study, melt-blown polypropylene (PP) nonwovens were used as substrates for the metallic deposition of copper. The substrates were pretreated by O_2 plasma, followed by treatments such as sensitization, activation, and reduction. The effects of the copper sulfate concentration, reaction temperature, and plasma power on the conductivity and adhesion strength of the PP nonwovens were investigated after copper deposition. The morphology of the PP nonwovens after copper deposition, analyzed by scanning electron microscopy and atomic force microscopy, revealed that copper nanoclusters were deposited on the fiber surface with a smooth surface morphology and dense structure. X-ray photoelectron spectroscopy indicated that the copper was present mainly in the form of the elementary substance, which coexisted with a little Cu~(2+).
机译:在这项研究中,熔喷聚丙烯(PP)非织造布用作铜金属沉积的基材。用O_2等离子体预处理底物,然后进行诸如敏化,活化和还原的处理。沉积铜后,研究了硫酸铜浓度,反应温度和等离子体功率对PP非织造布电导率和粘合强度的影响。通过扫描电子显微镜和原子力显微镜分析,铜沉积后的PP非织造布的形态表明,铜纳米团簇沉积在纤维表面上,具有光滑的表面形态和致密的结构。 X射线光电子能谱表明,铜主要以单质形式存在,并与少量Cu〜(2+)共存。

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