Application of reactive solvents of melamine for synthesis of polyetherols with perhydro-1,3,5-triazine rings

Wilk K.; Lubczak J.

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Application of reactive solvents of melamine for synthesis of polyetherols with perhydro-1,3,5-triazine rings

机译：三聚氰胺反应溶剂在合成具有过氢-1,3,5-三嗪环的聚醚醇中的应用

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The application of reactive solvents (RSs), namely hydroxymethyl derivatives of acetone for digestion of isocyanuric acid, which is insoluble in most organic solvents except for DMSO, makes the substrate available for further conversions. At this step, the incorporation of perhydro-1,3,5-triazine ring into RS takes place. The obtained solutions were used for synthesis of polyetherols containing perhydro-1,3,5-triazine rings in reaction with oxiranes: ethylene and propylene oxides. The polyetherols were then used to obtain foamed polyurethanes with enhanced thermal stability.

机译：反应性溶剂（RSs）的应用，即丙酮的羟甲基衍生物用于消化异氰尿酸，该溶剂不溶于DMSO以外的大多数有机溶剂，从而使底物可用于进一步转化。在这一步骤，将过氢的1,3,5-三嗪环并入RS。所获得的溶液用于在与环氧乙烷：环氧乙烷和环氧丙烷的反应中合成含有全氢-1,3,5-三嗪环的聚醚醇。然后将聚醚醇用于获得具有增强的热稳定性的泡沫聚氨酯。

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《Journal of Applied Polymer Science》 |2011年第2期|共10页
作者
Wilk K.; Lubczak J.;
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正文语种 eng
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heteroatom-containing polymers; oligomers; polyurethanes; reactive processing;

机译：含杂原子的聚合物;低聚物;聚氨酯;反应性加工;

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1. Application of reactive solvents of melamine for synthesis of polyetherols with perhydro-1,3,5-triazine rings [J] . Wilk K., Lubczak J. Journal of Applied Polymer Science . 2011,第2期

机译：三聚氰胺反应溶剂在合成具有过氢-1,3,5-三嗪环的聚醚醇中的应用
2. Application of glycidol in synthesis of oligoetherols with perhydro-1,3,5-triazine ring [J] . Cyzio K., Lubczak J. Journal of Applied Polymer Science . 2011,第1期

机译：缩水甘油在具有过水-1,3,5-三嗪环的低聚醚醇合成中的应用
3. Application of products of reaction between melamine and glycidol as substrates for oligoetherols and polyurethane foams containing 1,3,5-triazine rings [J] . Karina Cyzio, Jacek Lubczak Polymer international . 2013,第12期

机译：三聚氰胺与缩水甘油之间的反应产物作为低聚醚醇和含有1,3,5-三嗪环的聚氨酯泡沫的底物的应用
4. Synthesis of potassium salts of 2,4-diamino(alkylamino)-6-dinitromethyl-1,3,5-triazine and 2-hydrazinyl-4-amino(alkylamino)-6-dinitromethyl-1,3,5-triazine [C] . Alexander A. Gidaspov, Vladimir V. Bakharev, Olga V. Golovina, Seminar on New Trends in Research of Energetic Materials . 2014

机译：2,4-二氨基（烷基氨基）-6-二硝基甲基-1,3,5-三嗪和2-肼基-4-氨基（烷基氨基）-6-二硝基甲基-1,3,5-三嗪的钾盐的合成
5. Synthesis and evaluation of 1,3,5-triazine derivatives of amino acids for enantiomeric resolution of amine drugs. [D] . Ayub, Muhammed. 1998

机译：氨基酸1,3,5-三嗪衍生物的合成和评估，用于胺类药物的对映体拆分。
6. SYNTHESIS OF 2-33′-DI-(TERT-BUTOXYCARBONYL)-AMINODIPROPYLAMINE-46-DICHLORO-135-TRIAZINE AS A MONOMER AND 135-TRIS-PIPERAZINE-TRIAZINE AS A CORE FOR THE LARGE SCALE SYNTHESIS OF MELAMINE (TRIAZINE) DENDRIMERS [O] . Abdellatif Chouai, Vincent J. Venditto, Eric E. Simanek, -1

机译：2- 33-二-（叔丁氧羰基）-酰胺基二丙胺 -46-二氯-135-三嗪作为单体和135- 三嗪-哌嗪的合成-三嗪作为大规模合成三聚氰胺（三嗪）树枝状化合物的核心
7. SYNTHESIS OF 2-3,3'-DI-(TERT-BUTOXYCARBONYL)-AMINODIPROPYLAMINE-4,6,-DICHLORO-1,3,5-TRIAZINE AS A MONOMER AND 1,3,5-TRIS-PIPERAZINE-TRIAZINE AS A CORE FOR THE LARGE SCALE SYNTHESIS OF MELAMINE (TRIAZINE) DENDRIMERS [O] . 2009

机译：合成2- 3,3'-二羰基羰基） - 氨基二丙基胺 -4,6 ,--二氯-1,3,5-三嗪作为单体和1,3,5-βTris-piperazine - 三嗪作为三聚氰胺的大规模合成的核心（三嗪）树枝状大分子
8. Results of a Local Lymph Node Assay in Mice (LLNA/IMDS) with Toluene Diisocyanate based adduct in Organic Solvent (TDI Trimer) 1,3,5-Triazine- 2,4,6(1H,3H,5H)-trione, 1,3,5-tris(3-isocya natomethylphenyl). [R] . 2011

机译：基于甲苯二异氰酸酯的有机溶剂加成物（TDI三聚体）1,3,5-三嗪-2,4,6（1H，3H，5H） - 三酮，1小鼠局部淋巴结检测结果（LLNa / ImDs），3,5-三（3-isocya natomethylphenyl）。

Application of reactive solvents of melamine for synthesis of polyetherols with perhydro-1,3,5-triazine rings

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