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Synthesis, characterization, and application of polyethersulfone bound-iminodiacetic acid

机译:聚醚砜键合亚氨基二乙酸的合成,表征及应用

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摘要

A new method to introduce iminodiacetic acid (IDA) onto polyethersulfone (PES) matrix through chlorosulfonation was described in this work, and the prepared PES-IDA was used as adsorbent for the removal of metal ions from aqueous solutions. Chlorosulfonic groups (-SO_2Cl) were introduced onto PES first, then IDA was grafted onto PES by using the interactions between the chlorosulfonic group and the imino group of IDA. The grafted IDA was characterized by fourier transform infrared measurement, X-ray photoelectron spectroscopy analysis, and thermogravimetric analysis spectra. The adsorbed amounts by the PES-IDA for Cu~(2+) and Ag~+ were 3.44 mg/g and 7.09 mg/g, respectively. The PES-IDA adsorbent may expand the usage of PES in purification fields and could make some potential contributions to the polymer-based adsorbents.
机译:本文介绍了一种通过氯磺化将亚氨基二乙酸(IDA)引入聚醚砜(PES)基质的新方法,并将制备的PES-IDA用作吸附剂,用于从水溶液中去除金属离子。首先将氯磺酸基团(-SO_2Cl)引入到PES上,然后利用IDA的氯磺酸基团与亚氨基的相互作用将IDA接枝到PES上。通过傅里叶变换红外测量,X射线光电子能谱分析和热重分析光谱对接枝的IDA进行了表征。 PES-IDA对Cu〜(2+)和Ag〜+的吸附量分别为3.44 mg / g和7.09 mg / g。 PES-IDA吸附剂可能会扩大PES在纯化领域的用途,并可能对基于聚合物的吸附剂做出一些潜在贡献。

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