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Synthesis and characterization of phenol-formaldehyde microcapsules containing linseed oil and its use in epoxy for self-healing and anticorrosive coating

机译:含亚麻籽油的苯酚甲醛微胶囊的合成,表征及其在环氧自修复防腐涂料中的应用

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摘要

Phenol-formaldehyde microcapsules with linseed oil as an active agent were produced by applying in situ polymerization method. The anticorrosion and self-healing efficiency of the synthesized materials were studied. Characteristics of these synthesized capsules were studied by Fourier transform infrared spectroscopy, and surface morphology was analyzed by using scanning electron microscope. Controllable particle size was estimated at different rpm of stirrer and particle size was checked under microscope and also by using particle size analyzer. The anticorrosion performance of encapsulated microcapsules coated with epoxy resin was carried out in 5% NaCl aqueous solution. The effectiveness of linseed oil filled microcapsules was investigated for healing the cracks generated in paint films or coatings. It was found that the cracks were successfully healed when linseed oil was released from ruptured microcapsules. Further, linseed oil-healed area was found to prevent effectively the corrosion of the substrate in immersion studies.
机译:以亚麻籽油为活性剂,采用原位聚合法制备了酚醛甲醛微胶囊。研究了合成材料的防腐性能和自修复效率。通过傅立叶变换红外光谱研究了这些合成胶囊的特性,并使用扫描电子显微镜分析了表面形态。在搅拌器的不同转速下估计可控制的粒度,并在显微镜下和使用粒度分析仪检查粒度。在5%NaCl水溶液中进行了环氧树脂包封的微胶囊的防腐性能。研究了亚麻籽油填充的微胶囊对修复漆膜或涂料中产生的裂纹的有效性。结果发现,当亚麻籽油从破裂的微胶囊中释放出来时,裂缝就被成功治愈了。此外,在浸没研究中发现亚麻籽油已愈合的区域可有效防止基材腐蚀。

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