首页> 外文期刊>Journal of Applied Polymer Science >Effects of graphene nanosheets on the dielectric, mechanical, thermal properties, and rheological behaviors of poly(arylene ether nitriles)
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Effects of graphene nanosheets on the dielectric, mechanical, thermal properties, and rheological behaviors of poly(arylene ether nitriles)

机译:石墨烯纳米片对聚(亚芳基醚腈)的介电,机械,热性能和流变行为的影响

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摘要

Poly(arylene ether nitriles) (PEN) containing various contents of graphene nanosheets (GNs) was prepared via solution-casting method and investigated for their dielectric, mechanical, thermal, and rheological properties. For PEN/GNs nanocomposite with 5 wt % GNs, the dielectric constant was increased to 9.0 compared with that of neat PEN (3.1) and dielectric losses of all nanocomposites were in the range of 0.019-0.023 at 1 kHz. The tensile modulus and strength were increased about 6 and 14% with 0.5% GNs, respectively. The fracture surfaces of the all PEN/GNs nanocomposites revealed that GNs had good adhesion to PEN matrix. The thermal properties of the nanocomposites showed significant increase with increasing GN loading. For 5 wt % GNs-reinforced PEN nanocomposite, the temperatures corresponding to a weight loss of 5 wt % (T _(d5)%) and 30 wt % (T _(d30)%) increased by about 20 and 13°C, respectively. Rheological properties of the PEN nanocomposites showed a sudden change with the GN fraction and the percolation threshold was about 1 wt % of GNs.
机译:通过溶液流延法制备了包含各种含量的石墨烯纳米片(GNs)的聚(亚芳基醚腈)(PEN),并研究了它们的介电,机械,热和流变性能。对于具有5 wt%GNs的PEN / GNs纳米复合材料,与纯PEN(3.1)相比,介电常数增加到9.0,并且所有纳米复合材料在1 kHz时的介电损耗在0.019-0.023范围内。 GNs为0.5%时,拉伸模量和强度分别提高了约6%和14%。所有PEN / GNs纳米复合材料的断裂表面均显示GNs对PEN基质具有良好的粘附性。纳米复合材料的热性能随着GN含量的增加而显着增加。对于5 wt%GNs增强的PEN纳米复合材料,对应于5 wt%(T _(d5)%)和30 wt%(T _(d30)%)的重量损失的温度分别提高了20和13°C,分别。 PEN纳米复合材料的流变特性显示出随着GN分数的突然变化,渗透阈值约为GNs的1 wt%。

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