首页> 外文期刊>Journal of Applied Polymer Science >Coincorporation of nano-silica and nano-calcium carbonate in polypropylene
【24h】

Coincorporation of nano-silica and nano-calcium carbonate in polypropylene

机译:纳米二氧化硅和纳米碳酸钙在聚丙烯中的共混

获取原文
获取原文并翻译 | 示例
           

摘要

In this study, various polypropylene (PP) nanocomposites were prepared by melt blending method. The effects of different spherical nanofillers, such as 50 nm CaCO_3 and 20 nm SiO_2, on the linear viscoelastic property, crystallization behavior, morphology and mechanical property of the resulting PP nanocomposites were examined. Rheological study indicated that coincorporation of nano-SiO_2 and nano-CaCO_3 favored the uniform dispersion of nanoparticles in the PP matrix. Differential scanning calorimeter (DSC) and polarizing optical microscopy (POM) studies revealed that the coincorporation of SiO_2 and CaCO_3 nanoparticles could effectively improve PP crystallizability, which gave rise to a lower supercooling temperature (ΔT), a shorter crystallization half-life (t _(1/2)) and a smaller spherulite size in comparison with those nanocomposites incorporating only one type of CaCO_3 or SiO _2 nanoparticles. The mechanical analysis results also showed that addition of two types of nanoparticles into PP matrix gave rise to enhanced performance than the nanocomposites containing CaCO_3 or SiO _2 individually.
机译:在这项研究中,通过熔融共混方法制备了各种聚丙烯(PP)纳米复合材料。研究了不同球形纳米填料(如50 nm CaCO_3和20 nm SiO_2)对所得PP纳米复合材料的线性粘弹性,结晶行为,形貌和力学性能的影响。流变学研究表明,纳米SiO_2和纳米CaCO_3的共混促进了纳米颗粒在PP基体中的均匀分散。差示扫描量热仪(DSC)和偏振光学显微镜(POM)研究表明,SiO_2和CaCO_3纳米颗粒的共混可以有效改善PP的结晶性,从而降低了过冷温度(ΔT),缩短了结晶半衰期(t _ (1/2))和与仅掺入一种类型的CaCO_3或SiO _2纳米颗粒的纳米复合材料相比,较小的球晶尺寸。力学分析结果还表明,与单独包含CaCO_3或SiO _2的纳米复合材料相比,将两种类型的纳米颗粒添加到PP基体中可提高性能。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号