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Mesua ferrea L. seed oil based amido-amine modified nanoclay/epoxy nanocomposites

机译:Mesua ferrea L.种子油基酰胺基胺改性的纳米粘土/环氧树脂纳米复合材料

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摘要

Hydrophilic bentonite and organo-montmorillonite (OMMT) have been modified by using a vegetable oil based amido-amine compound. The modified nanoclays were characterized by using X-ray diffraction (XRD) and FTIR techniques. Increase in the basal spacing after the modification was observed in both the cases. Further, Mesua ferrea L. seed oil based sulfonated epoxy resin nanocomposites have been prepared by using these modified nanoclays [3 (w/w) of clay in each case]. The XRD, TEM, SEM, FTIR, and rheological studies confirmed the formation of partially exfoliated nanocomposites. The study also confirmed that hydrophilic bentonite is not suitable nanofiller for the system, though modified bentonite slightly improves the performance characteristics of the pristine polymer. Modified OMMT based nanocomposite shows significant improvement in tensile strength (~ 1.7 times), scratch hardness (~ 2 times), gloss (14 units), and thermal stability (18°C) compared to the pristine system. This nanocomposite also exhibit better performance than OMMT based analogous nanocomposite.
机译:亲水性膨润土和有机蒙脱土(OMMT)已通过使用基于植物油的酰胺基胺化合物进行了改性。改性的纳米粘土通过使用X射线衍射(XRD)和FTIR技术进行了表征。在这两种情况下,均观察到修饰后的基底间距增加。此外,通过使用这些改性的纳米粘土[在每种情况下为粘土的3(w / w)]已经制备了Mesua ferrea L.种子油基磺化环氧树脂纳米复合材料。 XRD,TEM,SEM,FTIR和流变学研究证实了部分剥落的纳米复合材料的形成。该研究还证实,亲水性膨润土不适用于该系统,尽管改性膨润土会稍微改善原始聚合物的性能特征。与原始体系相比,改性的基于OMMT的纳米复合材料在拉伸强度(〜1.7倍),划痕硬度(〜2倍),光泽(14个单位)和热稳定性(18°C)方面显示出显着改善。该纳米复合材料还表现出比基于OMMT的类似纳米复合材料更好的性能。

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