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Toughening of epoxy resins by modified m-phenylene diamine having soft ether chain

机译:通过具有软醚链的改性间苯二胺对环氧树脂进行增韧

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摘要

A new soften curing agent for toughening epoxy resins was synthesized by m-phenylene diamine modified with epoxypropyl butyl ether. The curing processes of epoxy resin/modified m-phenylene diamine were traced by differential scanning calorimetry (DSC), then kinetic parameters, ΔE and n, were deduced. Fourier transform infrared (FTIR) analysis showed that the longer the reaction time was, the smaller the absorption peaks of epoxy group were. The results of the mechanical properties demonstrated that the impact property of the epoxy resin cured by modified m-phenylene diamine at the moderate temperature was better than that of cured by unmodified one because of the introduction of soft ether chain.
机译:通过用环氧丙基丁醚改性的间苯二胺合成了一种新型的环氧树脂增韧软化剂。通过差示扫描量热法(DSC)追踪了环氧树脂/改性间苯二胺的固化过程,推导了动力学参数ΔE和n。傅立叶红外光谱分析表明,反应时间越长,环氧基的吸收峰越小。力学性能的结果表明,由于引入了软醚链,在中等温度下用改性的间苯二胺固化的环氧树脂的冲击性能要好于未经改性的对苯二胺固化的环氧树脂。

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