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Preparation and investigation of the β-nucleated polypropylene/ polystyrene blends

机译:β-成核聚丙烯/聚苯乙烯共混物的制备和研究

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摘要

In this work, β-polypropylene/polystyrene (β-PP/PS) blends were prepared with PP, PS, and a novel supported β-nucleating agent or β-nucleated PP and PS. The β-PP/PS blends were compatabilized by PP-g-MA, PP-g-GMA, POE-g-MA, and EVA-g-MA, respectively. For exploring the effect of PS amount and compatibilizers on the β-nucleation of PP, crystallization behavior and melting characteristics, the β-crystal content and crystal morphology of β-PP are characterized by differential scanning calorimetry (DSC), wide angle X-ray diffraction (WAXD), and polarized light microscopy (POM). The results indicated that the PP with high content of β-crystal was obtained by addition of CaCO _3 supported β-nucleating agent (β-NA) into PP. The β-nucleation, crystallization behavior, and melting characteristics, and the β-crystal content of β-PP in these blends were not influenced by addition of PS and its amount. However, the increased content of PS decreased the size of β-spherulites of PP in these blends. The β-nucleation of PP in compatabilized blends slightly depended on the compatibilizers. β-PP/PS blends with high β-crystal content can easily be prepared.
机译:在这项工作中,使用PP,PS和新型负载型β成核剂或β成核的PP和PS制备了β-聚丙烯/聚苯乙烯(β-PP/ PS)共混物。 β-PP/ PS共混物分别通过PP-g-MA,PP-g-GMA,POE-g-MA和EVA-g-MA相容。为了探索PS量和相容剂对PPβ形核,结晶行为和熔融特性的影响,通过差示扫描量热法(DSC),广角X射线分析表征了β-PP的β晶体含量和晶体形态。衍射(WAXD)和偏振光显微镜(POM)。结果表明,通过将CaCO 3负载的β-成核剂(β-NA)添加到PP中获得了具有高β-晶体含量的PP。这些共混物中的β-成核,结晶行为和熔融特性以及β-PP的β-结晶含量不受PS的添加及其含量的影响。然而,这些混合物中PS含量的增加降低了PPβ-球晶的尺寸。相容性共混物中PP的β成核作用略微取决于相容剂。可以容易地制备具有高β-晶体含量的β-PP/ PS共混物。

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