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The effect of pentaerythritol-aluminum on the thermal stability of rigid poly(vinyl chloride)

机译:季戊四醇铝对硬质聚氯乙烯热稳定性的影响

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摘要

Pentaerythritol-aluminum (PE-Al) was synthesized by a solid-phase reaction in this study. The formation and characteristics of PE-Al were confirmed by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). SEM images showed that the shapes of PE-Al particles were spherical and the average size was around 23 nm. The thermal properties of rigid poly(vinyl chloride) (PVC) with PE-Al were tested by Congo red test, thermal aging test, conductivity test, thermogravimetric analysis (TGA), and UV-visible spectroscopy test. The results showed that combination of PE-Al, in comparison with commercial thermal stabilizers, presented an obvious improvement in stabilization efficiency of PVC. Moreover, addition of PE-Al could significantly prolong static stability time of PVC, reduce weight loss, and improve the initial color of PVC films.
机译:本研究通过固相反应合成了季戊四醇-铝(PE-Al)。通过扫描电子显微镜(SEM)和傅立叶变换红外光谱(FTIR)确认了PE-Al的形成和特性。 SEM图像表明,PE-Al颗粒的形状为球形,平均粒径约为23 nm。通过刚果红测试,热老化测试,电导率测试,热重分析(TGA)和紫外可见光谱测试,测试了带有PE-Al的硬质聚氯乙烯(PVC)的热性能。结果表明,与市售的热稳定剂相比,PE-Al的组合对PVC的稳定效率有明显的改善。而且,添加PE-Al可以显着延长PVC的静电稳定时间,减少重量损失,并改善PVC膜的初始颜色。

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