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Soybean and linseed oil-based composites reinforced with wood flour and wood fibers

机译:木粉和木纤维增强的大豆和亚麻籽油基复合材料

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摘要

Composites consisting of a conjugated linseed or soybean oil-based thermoset reinforced with wood flour and wood fibers have been prepared by free radical polymerization. The thermoset resin consists of a copolymer of conjugated linseed oil (CLO) or conjugated soybean oil (CSO), n-butyl methacrylate (BMA), divinylbenzene (DVB), and maleic anhydride (MA). The composites were cured at 180°C and 600 psi and postcured for 2 h at 200°C under atmospheric pressure. The effect of varying filler load, time of cure, filler particle size, origin of the fillers, and resin composition has been assessed by means of tensile tests, DMA, TGA, Soxhlet extraction followed by ~1H-NMR spectroscopic analysis of the extracts, and DSC. The best processing conditions have been established for the pine wood flour composites. It has been observed that the addition of MA to the resin composition improves the filler-resin interaction.
机译:已经通过自由基聚合制备了由木粉和木纤维增强的基于共轭亚麻籽或大豆油的热固性复合材料。该热固性树脂由共轭亚麻子油(CLO)或共轭大豆油(CSO),甲基丙烯酸正丁酯(BMA),二乙烯基苯(DVB)和马来酸酐(MA)的共聚物组成。将复合物在180℃和600psi下固化,并在大气压下在200℃下后固化2小时。通过拉伸试验,DMA,TGA,索氏提取,然后用〜1H-NMR光谱分析法评估了变化的填料负载量,固化时间,填料粒度,填料来源和树脂组成的影响,和DSC。已经为松木粉复合材料确定了最佳加工条件。已经观察到,向树脂组合物中添加MA改善了填料-树脂相互作用。

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