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Superhydrophobic polyurethane and silica nanoparticles coating with high transparency and fluorescence

机译:具有高透明度和荧光性的超疏水聚氨酯和二氧化硅纳米粒子涂料

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摘要

A superhydrophobic surface was prepared by spin-coating trimethylsiloxane functionalized SiO_2 (TMS-SiO_2) solutions onto a precoated polyurethane (PU) layer. The superhydrophobic coatings showed high stability with time, and the prepared coatings remained superhydrophobicity even after 6 months. Furthermore, the as-prepared surface showed high transparency with a transmittance above 70% in visible light region (400-800 nm). The transition of the composite surface from superhydrophobicity to hydrophilicity can be achieved by increasing the drying temperature. More interestingly, the surface showed excellent fluorescent property by the incorporation of fluorescent Europium (Eu) complex into the surface and without deteriorating the superhydrophobic and transparent properties. It was believed that the superhydrophobic surface with multifunction would broaden the applications of superhydrophobic materials.
机译:通过将三甲基硅氧烷官能化的SiO_2(TMS-SiO_2)溶液旋涂到预涂的聚氨酯(PU)层上来制备超疏水表面。该超疏水涂层显示出高的经时稳定性,并且所制备的涂层甚至在6个月后仍保持超疏水性。此外,所制备的表面显示出高透明性,在可见光区域(400-800nm)中的透射率高于70%。复合表面从超疏水性向亲水性的转变可以通过提高干燥温度来实现。更有趣的是,该表面通过将荧光Euro(Eu)络合物掺入表面而显示出优异的荧光性能,并且不会降低超疏水性和透明性。相信具有多功能的超疏水表面将拓宽超疏水材料的应用。

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