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Effect of epoxidized natural rubber on the properties of rectorite/carbon blackatural rubber nanocomposites

机译:环氧天然橡胶对累托石/炭黑/天然橡胶纳米复合材料性能的影响

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摘要

Epoxidized natural rubber (ENR) was introduced into rectorite (REC)/carbon blackatural rubber (NR) nanocomposites by two ways: (1) the direct incorporation of ENR and (b) the incorporation of a spray-dried REC/ENR compound. Transmission electron microscopy and X-ray diffraction analysis showed that the REC layers presented a nanodispersion structure in the REC/ENR compound. The vulcanization characteristics indicated that ENR increased the crosslinking density of the composites. The stronger reaction between the REC layers and ENR was verified by Fourier transform infrared spectroscopy in the spray-dried REC/ENR compound blended with NR versus that in the REC/NR master batch blended with ENR. As a result, the physical properties, such as the mechanical properties, cutting and chipping resistance, and abrasion resistance, of the composites were greatly increased by the addition of the REC/ENR compound.
机译:通过两种方式将环氧化天然橡胶(ENR)引入累托石(REC)/炭黑/天然橡胶(NR)纳米复合材料中:(1)直接掺入ENR和(b)掺入喷雾干燥的REC / ENR化合物。透射电子显微镜和X射线衍射分析表明,REC层在REC / ENR化合物中呈现出纳米分散结构。硫化特性表明ENR增加了复合材料的交联密度。在与NR混合的喷雾干燥REC / ENR化合物中,与在ENR混合的REC / NR母料中相比,通过傅里叶变换红外光谱证实了REC层与ENR之间的较强反应。结果,通过添加REC / ENR化合物,极大地提高了复合材料的物理性能,例如机械性能,耐切割和抗碎裂性以及耐磨性。

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