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首页> 外文期刊>Journal of Applied Polymer Science >Compatibilization of bentonite filled ethylene-propylene-diene monomer composites: Effect of maleic anhydride grafted EPDM
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Compatibilization of bentonite filled ethylene-propylene-diene monomer composites: Effect of maleic anhydride grafted EPDM

机译:膨润土填充的乙烯-丙烯-二烯单体复合材料的相容性:马来酸酐接枝三元乙丙橡胶的效果

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摘要

Maleic anhydride grafted ethylene-propylene-diene monomer (MAH-g-EPDM) was prepared by peroxide-initiated melt grafting of MAH onto EPDM using a HAAKE internal mixer at 180°C and 60 rpm for 5 min and it was used as compatibilizer to enhance the compatibility of EPDM/Bt composites. The composites were prepared using a laboratory scale two roll mill, model XK-160 at room temperature. The addition of 10 parts per hundred rubber (phr) of MAH-g-EPDM into EPDM/Bt composite results in significantly improved tensile properties compared with the uncompatibilized EPDM/Bt composites. Curing behavior, tensile properties, solvent resistance, and the rubber-filler interaction of compatibilized and uncompatibilized EPDM/Bt composites were investigated. The cure time (t _(90)), scorch time (t _(S 2)), maximum torque (M _H), and minimum torque (M _L) of compatibilized composites were increased upon addition of MAH-g-EPDM. Compared with uncompatibilized EPDM/Bt composites, the tensile properties, solvent resistance, and rubber-filler interaction of compatibilized EPDM/Bt composites were all improved. SEM micrographs of tensile fractured surfaces of compatibilized EPDM/Bt composites showed a better dispersion of Bt and interfacial adhesion between EPDM and Bt compared with uncompatibilized EPDM/Bt composites.
机译:马来酸酐接枝的乙烯-丙烯-二烯单体(MAH-g-EPDM)通过使用HAAKE内部混合器在180°C和60 rpm下过氧化物引发的MAH的过氧化物引发的熔融接枝到EPDM上来制备,并用作相容剂增强了EPDM / Bt复合材料的相容性。使用实验室规模的两辊轧机,型号XK-160在室温下制备复合材料。与不相容的EPDM / Bt复合材料相比,在EPDM / Bt复合材料中每100橡胶(phr)的MAH-g-EPDM橡胶添加10份,可显着改善拉伸性能。研究了相容和不相容的EPDM / Bt复合材料的固化行为,拉伸性能,耐溶剂性以及橡胶与填料的相互作用。加入MAH-g-EPDM后,相容性复合材料的固化时间(t _(90)),焦化时间(t _(S 2)),最大扭矩(M _H)和最小扭矩(M _L)增大。与不相容的EPDM / Bt复合材料相比,不相容的EPDM / Bt复合材料的拉伸性能,耐溶剂性和橡胶-填料相互作用都得到了改善。相容的EPDM / Bt复合材料的拉伸断裂表面的SEM显微照片显示,与不相容的EPDM / Bt复合材料相比,Bt的分散性和EPDM与Bt之间的界面粘合性更好。

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