Synthesis of highly loaded and well-controlled magnetic beads via emulsion polymerization

Kniajanski S.; Colborn R.E.; Bales B.C.; Riccobono O.; Dulgar-Tulloch A.J.; Stein J.; Kandapallil B.I.I.

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Synthesis of highly loaded and well-controlled magnetic beads via emulsion polymerization

机译：通过乳液聚合合成高负载和控制良好的磁珠

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Superparamagnetic iron oxide (SPIO) incorporated polystyrene beads of uniform size distribution (～170 nm) and high magnetic content (～40%) are synthesized by emulsion styrene polymerization in the presence of functionalized SPIO. The role of surface functionality on the polymerization process and SPIO incorporation is investigated by carrying out styrene emulsion polymerizations with different functionalities on SPIO. A unique combination of oleic acid and (2-acetoacetoxy) ethyl methacrylate as surface ligands for SPIO is used to attain the best magnetic beads.

机译：在功能化SPIO的存在下，通过乳液苯乙烯聚合法合成了尺寸分布均匀（〜170 nm）和高磁性含量（〜40％）的超顺磁性氧化铁（SPIO）聚苯乙烯珠。通过在SPIO上进行不同官能度的苯乙烯乳液聚合，研究了表面官能度在聚合过程和SPIO掺入中的作用。油酸和（2-乙酰乙酰氧基）甲基丙烯酸乙酯作为SPIO的表面配体的独特组合用于获得最佳磁珠。

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《Journal of Applied Polymer Science》 |2013年第4期|共8页
作者
Kniajanski S.; Colborn R.E.; Bales B.C.; Riccobono O.; Dulgar-Tulloch A.J.; Stein J.; Kandapallil B.I.I.;
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正文语种 eng
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关键词
emulsion; magnetic beads; polystyrene; superparamagnetic iron oxide;

机译：乳液;磁珠;聚苯乙烯;超顺磁性氧化铁;

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1. Synthesis of highly loaded and well-controlled magnetic beads via emulsion polymerization [J] . Kniajanski S., Colborn R.E., Bales B.C., Journal of Applied Polymer Science . 2013,第4期

机译：通过乳液聚合合成高负载和控制良好的磁珠
2. Nanobeads Highly Loaded with Superparamagnetic Nanoparticles Prepared by Emulsification and Seeded-Emulsion Polymerization [J] . Chantal Paquet, Lilianne Page, Arnold Kell, Langmuir: The ACS Journal of Surfaces and Colloids . 2010,第8期

机译：乳化和种子乳液聚合制备的超顺磁性纳米颗粒高负载纳米珠
3. Eucalyptus Oil Emulsion Loaded Biodegradable Polymeric Beads as a Bio-Larvicide Agent Against Culex Tritaeniorhynchus [J] . Saranya Sugumar, Devichand Chandrakar, G. Kanimozhi, Advanced Science, Engineering and Medicine . 2015,第2期

机译：桉树油乳液负载的可生物降解的聚合物珠粒作为抗库蚊Tritaeniorhynchus的生物杀菌剂
4. A Novel Approach to Prepare Hydroxyapatite-Coated Biodegradable Polymer Microspheres Loaded with Magnetic Fe_3O_4 via NanoparticEe-Stabilized Emulsions [C] . Masahiro Okada, Shoji Takeda, Tsutomu Furuzono Symposium and Annual Meeting of International Society for Ceramics in medicine . 2013

机译：一种制备羟基磷灰石涂覆的可生物降解聚合物微球的新方法，纳米氨基稳定乳液负载磁FE_3O_4
5. Anionic synthesis of highly isotactic polystyrene in the presence of lithium hydroxides or lithium alkoxides, and, Controlled "living" emulsion polymerization of methyl methacrylate by atom transfer radical polymerization. [D] . Makino, Takayuki. 1997

机译：在氢氧化锂或烷氧基锂的存在下阴离子合成高度全同立构的聚苯乙烯，以及通过原子转移自由基聚合进行甲基丙烯酸甲酯的受控“活”乳液聚合。
6. Synthesis and characterization of noscapine loaded magnetic polymeric nanoparticles [O] . Mohamed O. Abdalla, Ritu Aneja, Derrick Dean, -1

机译：八峰负载磁聚合物纳米粒子的合成与表征
7. Nanobeads highly loaded with superparamagnetic nanoparticles prepared by emulsification and seeded-emulsion polymerization [O] . Paquet, Chantal, Page, Lilianne, Kell, Arnold, 2010

机译：通过乳化和种子乳液聚合制得的超顺磁性纳米粒子高负载的纳米珠
8. Model Filled Polymers 8. Synthesis of Crosslinked Polymeric Beads by SeedPolymerization [R] . Zou, D., Sun, L., Aklonis, J. J., 1991

机译：模型填充聚合物8.通过种子聚合合成交联聚合物珠粒

Synthesis of highly loaded and well-controlled magnetic beads via emulsion polymerization

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