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Rheological and aging properties of ultraviolet absorber/styrene-butadiene- styrene-modified bitumens

机译:紫外线吸收剂/苯乙烯-丁二烯-苯乙烯改性沥青的流变和老化性能

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The prevention of the ultraviolet (UV) aging of styrene-butadiene-styrene (SBS)-modified bitumen is of great significance because UV aging is considered to be a critical factor in the deterioration of the performance of bituminous roads. In this study, we selected two UV absorbers (octabenzone and bumetrizole) as modifiers to evaluate their effects on the rheological and UV-aging properties of different SBS-modified bitumens (linear and radial types) by means of dynamic shear rheological testing. The thermooxidative aging of the binders was also investigated through thin-film oven testing. The results show that for the linear- and radial-SBS-modified bitumens, octabenzone only enhanced their elasticity at high temperatures, but bumetrizole could increase the elastic response at intermediate temperatures on the one hand and the viscous response at high temperatures on the other hand. The UV aging of the radial-SBS-modified bitumens could effectively be alleviated by both octabenzone and bumetrizole, whereas that of the linear ones could only be improved by bumetrizole. The influence of the UV absorbers on the thermooxidative-aging properties of the SBS-modified bitumens was dependent on the types of UV absorbers and SBS polymers.
机译:防止苯乙烯-丁二烯-苯乙烯(SBS)改性沥青的紫外线(UV)老化具有重要意义,因为紫外线老化被认为是导致沥青路面性能下降的关键因素。在这项研究中,我们选择了两种紫外线吸收剂(八苯并萘和丁二唑)作为改性剂,以通过动态剪切流变测试评估它们对不同SBS改性沥青(线性和径向类型)的流变和UV老化性能的影响。还通过薄膜烘箱测试研究了粘合剂的热氧化老化。结果表明,对于线性和径向SBS改性的沥青,八氮苯仅在高温下会增强其弹性,而丁苯咪唑一方面可以在中间温度下增加弹性响应,另一方面可以在高温下增加粘性响应。 。八溴二苯醚和丁苯咪唑均可有效缓解放射状SBS改性沥青的UV老化,而线形SBS改性沥青仅可通过丁苯唑改善。紫外线吸收剂对SBS改性沥青的热氧化老化性能的影响取决于紫外线吸收剂和SBS聚合物的类型。

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