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Probing the reinforcing mechanism of graphene and graphene oxide in natural rubber

机译:探讨天然橡胶中石墨烯和氧化石墨烯的增强机理

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摘要

Natural rubber (NR) containing graphene (GE) and graphene oxide (GO) were prepared by latex mixing. The in situ chemically reduction process in the latex was used to realize the conversion of GO to GE. A noticeable enhancement in tensile strength was achieved for both GO and GE filled NR systems, but GE has a better reinforcing effect than GO. The strain-induced crystallization was evaluated by synchrotron wide-angle X-ray diffraction. Increased crystallinity and special strain amplification effects were observed with the addition of GE. The incorporation of GE produces a faster strain-induced crystallization rate and a higher crystallinity compared to GO. The entanglement-bound tube model was used to characterize the chain network structure of composites. It was found that the contribution of entanglement to the conformational constraint increases and the network molecular parameters changes with the addition of GE and GO, while GE has a more evident effect than GO.
机译:通过胶乳混合制备含有石墨烯(GE)和氧化石墨烯(GO)的天然橡胶(NR)。乳胶中的原位化学还原过程用于实现GO向GE的转化。 GO和GE填充的NR系统均实现了明显的拉伸强度提高,但GE的增强效果比GO更好。通过同步加速器广角X射线衍射评估应变诱导的结晶。加入GE后,结晶度增加,应变增强效果增强。与GO相比,GE的掺入产生更快的应变诱导结晶速率和更高的结晶度。缠结管模型用于表征复合材料的链状网络结构。研究发现,随着GE和GO的加入,纠缠对构象约束的贡献增加,网络分子参数发生变化,而GE的作用比GO更明显。

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