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Preparation and characterization of acrylic acid/itaconic acid hydrogel coatings containing silver nanoparticles

机译:含银纳米粒子的丙烯酸/衣康酸水凝胶涂层的制备与表征

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摘要

Hydrogel silver nanocomposites have been used in applications with excellent antibacterial performance. Acrylic acid (AA)/itaconic acid (IA) hydrogels silver nanocomposites were prepared and applied as a coating on a textile substrate. Hydrogel matrices were synthesized first by the polymerization of an AA/IA aqueous (80/20 v/v) solution and mixed with 2-2-azobis(2-methylpropionamide) diclorohydrate and N,N′-methylene bisacrylamide until the hydrogel was formed. Silver nanoparticles were generated throughout the hydrogel networks with an in situ method via the incorporation of the silver ions and subsequent reduction with sodium borohydride. Cotton (C) and cotton/polyester (CP) textile fibers were then coated with these hydrogel silver nanocomposites. The influence of these nanocomposite hydrogels on the properties of the textile fiber were investigated by infrared spectroscopy (attenuated total reflectance), scanning electron microscopy, energy-dispersive X-ray spectroscopy, and antibacterial tests against Pseudomona aeruginosa and Staphylococcus aureus. The better conditions, in which no serious aggregation of the silver nanoparticles occurred, were determined. It was proven that the textiles coated with hydrogels containing nanosilver had an excellent antibacterial abilities.
机译:水凝胶银纳米复合材料已用于具有出色抗菌性能的应用中。制备了丙烯酸(AA)/衣康酸(IA)水凝胶银纳米复合材料,并将其作为涂层涂覆在纺织品基材上。首先通过AA / IA水溶液(80/20 v / v)的聚合合成水凝胶基质,然后将其与2-2-偶氮双(2-甲基丙酰胺)二氯水合物和N,N'-亚甲基双丙烯酰胺混合直至形成水凝胶。通过引入银离子并随后用硼氢化钠还原,通过原位方法在整个水凝胶网络中生成了银纳米颗粒。然后用这些水凝胶银纳米复合材料涂覆棉(C)和棉/聚酯(CP)纺织纤维。通过红外光谱(衰减的全反射率),扫描电子显微镜,能量色散X射线光谱以及对铜绿假单胞菌和金黄色葡萄球菌的抗菌测试,研究了这些纳米复合水凝胶对纺织纤维性能的影响。确定了更好的条件,其中没有发生银纳米颗粒的严重聚集。事实证明,涂有含纳米银的水凝胶的纺织品具有出色的抗菌能力。

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