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Study of Thermodegradation and Thermostabilization of Poly(lactide acid) Using Subsequent Extrusion Cycles

机译:利用随后的挤出循环研究聚丙交酯酸的热降解和热稳定化

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摘要

The thermomechanical degradation and thermostabilization of poly(lactic acid) (PLA) have been studied using subsequent extrusion cycles under different temperature profiles. Primary and secondary antioxidants were used to avoid degradation process during extrusion. Melt flow index (MFI), size exclusion chromatography (SEC), and infrared spectroscopy (FTIR) analysis were used to evaluate the degradation and stabilization of PLA. The MFI and SEC analysis show that the main thermodegradation mechanism of PLA is governed by scission reactions. FTIR analysis confirmed the SEC results and showed that the synergetic effect between primary and secondary antioxidant is a suitable way to thermostabilize the PLA.
机译:聚乳酸(PLA)的热机械降解和热稳定度已使用不同温度曲线下的后续挤出循环进行了研究。一级和二级抗氧化剂用于避免挤出过程中的降解过程。熔体流动指数(MFI),尺寸排阻色谱(SEC)和红外光谱(FTIR)分析用于评估PLA的降解和稳定性。 MFI和SEC分析表明,PLA的主要热降解机理受断裂反应控制。 FTIR分析证实了SEC的结果,并表明一级和二级抗氧化剂之间的协同作用是使PLA热稳定的合适方法。

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