Conductivity and Intermolecular Interactions in Proton-Conducting Gel Electrolytes

Liudmila E. Shmukler; Nguyen Van Thuc; Yulia A. Fadeeva; Liubov P. Safonova

首页> 外文期刊>Journal of Applied Polymer Science >Conductivity and Intermolecular Interactions in Proton-Conducting Gel Electrolytes

【24h】

Conductivity and Intermolecular Interactions in Proton-Conducting Gel Electrolytes

机译：质子传导凝胶电解质中的电导率和分子间相互作用

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Proton-conducting gel electrolytes based on poly(methyl methacrylate) (PMMA), poly(vinylidene fluoride) (PVdF), and mixtures of PMMA with PVdF or poly(vinyl chloride) doped by acid solutions in aprotic solvents were synthesized and are discussed in this article. The gel conductivity as a function of the concentrations of acid and polymer and the polymeric matrix composition has been analyzed. Extreme dependence of the conductivity on acid and polymer concentrations was found. It was revealed that within the acid concentration range studied, the gel conductivity was higher than the conductivity of the corresponding liquid electrolytes used for the synthesis. The increase in the electrical conductivity with the growth of the systems viscosity is discussed as an indication of a certain involvement of the polymer matrix in the increase of the charge carrier mobility within the frame of a Grotthuss mechanism.

机译：在质子惰性溶剂中合成了基于聚甲基丙烯酸甲酯（PMMA），聚偏二氟乙烯（PVdF）和PMMA与PVdF或酸溶液掺杂的聚氯乙烯的质子传导凝胶电解质，并在其中进行了讨论本文。已经分析了凝胶电导率与酸和聚合物以及聚合物基质组成的浓度的关系。发现电导率对酸和聚合物浓度的极端依赖性。发现在所研究的酸浓度范围内，凝胶电导率高于用于合成的相应液体电解质的电导率。讨论了随着系统粘度的增加而增加的电导率，作为聚合物基质一定程度参与格罗索斯机制框架内载流子迁移率增加的指示。

著录项

来源
《Journal of Applied Polymer Science》 |2014年第17期|共8页
作者
Liudmila E. Shmukler; Nguyen Van Thuc; Yulia A. Fadeeva; Liubov P. Safonova;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
conducting polymers; gels; properties and characterization; spectroscopy;

机译：导电聚合物;凝胶;性质和表征;光谱学;

相似文献

外文文献
中文文献
专利

1. Conductivity and Intermolecular Interactions in Proton-Conducting Gel Electrolytes [J] . Liudmila E. Shmukler, Nguyen Van Thuc, Yulia A. Fadeeva, Journal of Applied Polymer Science . 2014,第17期

机译：质子传导凝胶电解质中的电导率和分子间相互作用
2. Effect of donor number of solvent on the conductivity behaviour of nonaqueous proton-conducting polymer gel electrolytes [J] . Sekhon SS., Arora N., Singh HP. Solid state ionics . 2003,第3a4期

机译：溶剂给体数对非水质子传导聚合物凝胶电解质电导行为的影响
3. The effect of solvent and proton donor type on the conductivity and physico-chemical properties of poly(vinylidene fluoride)-based proton-conducting gel electrolytes [J] . Zukowska G., Wojda A., Zygadlo-Monikowska E., Solid state ionics . 2000,第Speca期

机译：溶剂和质子供体类型对聚偏二氟乙烯基质子传导凝胶电解质电导率和理化性质的影响
4. Relationship between Electrochemical Properties and Electrolyte Partial Conductivities of Proton-Conducting Ceramic Fuel Cells [C] . Y. Matsuzaki, Y. Tachikawa, T. Somekawa, International Symposium on Solid Oxide Fuel Cells . 2017

机译：质子传导陶瓷燃料电池电化学性能与电解质局部电导率的关系
5. Enhancement of ionic conductivity of solid and gel polymer electrolytes by nanoconfinement of electrolyte materials in alumina interpenetrating networks for room temperature lithium ion nanobattery applications. [D] . Jayasekara, Indumini U. 2016

机译：在室温互穿的锂离子纳米电池应用中，通过氧化铝互穿网络中电解质材料的纳米约束，可以提高固体和凝胶聚合物电解质的离子电导率。
6. Silica gel solid nanocomposite electrolytes with interfacial conductivity promotion exceeding the bulk Li-ion conductivity of the ionic liquid electrolyte filler [O] . Xubin Chen, Brecht Put, Akihiko Sagara, 2020

机译：界面导电性增强的硅胶固体纳米复合电解质离子液体电解质填充剂的整体锂离子电导率
7. Silica gel solid nanocomposite electrolytes with interfacial conductivity promotion exceeding the bulk Li-ion conductivity of the ionic liquid electrolyte filler [O] . Xubin Chen, Brecht Put, Akihiko Sagara, 2020

机译：硅胶固体纳米复合材料电解质具有界面电导率促进的电解质超过离子液体电解质填料的块状锂离子电导率

Conductivity and Intermolecular Interactions in Proton-Conducting Gel Electrolytes

摘要

著录项

相似文献

相关主题

期刊订阅