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Potential Role of Nanofillers as Compatibilizers in Immiscible PLA/LDPE Blends

机译:纳米填料在不相容的PLA / LDPE共混物中作为增容剂的潜在作用

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This article describes the use of commercial silica (SiO2) and calcium carbonate (CaCO3) nanofillers as compatibilizers in immiscible polylactide/low-density polyethylene (PLA/LDPE) blends. The general aim of the study was to investigate the possibilities of replacing standard commodity plastics such as LDPE based on non-renewable mineral oil resources with the biodegradable renewable polymer PLA in compatibilized PLA/LDPE blends for use in the packaging industry. The calculations of the minimal interfacial energy and optimal wetting abilities indicated that SiO2 filler was a better potential compatibilizer than CaCO3 for a given PLA/LDPE blend. This was due to its preferential localization at the interface. The significantly improved morphology of the ternary PLA/LDPE/SiO2 blend was found to present an increased strength, toughness, and crystallinity. (C) 2014 Wiley Periodicals, Inc.
机译:本文介绍了商用二氧化硅(SiO2)和碳酸钙(CaCO3)纳米填料在不混溶的聚丙交酯/低密度聚乙烯(PLA / LDPE)混合物中作为相容剂的用途。该研究的总体目的是研究在包装工业中使用的可相容的PLA / LDPE混合物中,用可生物降解的可再生聚合物PLA替代基于不可再生矿物油资源的标准商品塑料(例如LDPE)的可能性。最小界面能和最佳润湿能力的计算表明,对于给定的PLA / LDPE混合物,SiO2填料比CaCO3更好的潜在相容剂。这是由于其在接口上的优先本地化。发现三元PLA / LDPE / SiO 2共混物的形态显着改善,呈现出增加的强度,韧性和结晶度。 (C)2014威利期刊公司

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