Carbon Nanotubes Inhibit the Free-Radical Cross-Linking of Siloxane Polymers

Zhuo Li; Kyoung-sik Moon; Ziyin Lin; Yagang Yao; Stewart Wilkins; C. P. Wong

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Carbon Nanotubes Inhibit the Free-Radical Cross-Linking of Siloxane Polymers

机译：碳纳米管抑制硅氧烷聚合物的自由基交联

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Carbon nanotubes (CNTs) are found to inhibit the free-radical cross-linking of vinyl-terminated polydimethylsiloxane (PDMS) by trapping the free radicals in a CNT/PDMS composite. The cross-linking density values measured by swelling test, equilibrium stress-strain test, glass-transition temperature and Raman spectroscopy all decrease with the addition of CNTs. The inhibition effect is shown to be more significant with increased functionality and curvature in the CNTs used.

机译：发现碳纳米管（CNT）通过捕获CNT / PDMS复合材料中的自由基来抑制乙烯基封端的聚二甲基硅氧烷（PDMS）的自由基交联。通过溶胀试验，平衡应力应变试验，玻璃化转变温度和拉曼光谱法测得的交联密度值均随CNT的添加而降低。随着所用CNT的官能度和曲率的增加，抑制作用显示出更显着的作用。

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来源
《Journal of Applied Polymer Science》 |2014年第12期|共8页
作者
Zhuo Li; Kyoung-sik Moon; Ziyin Lin; Yagang Yao; Stewart Wilkins; C. P. Wong;
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正文语种 eng
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nanotubes; graphene and fullerenes; composites; crosslinking;

机译：纳米管;石墨烯和富勒烯;复合材料;交联;

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专利

1. Carbon Nanotubes Inhibit the Free-Radical Cross-Linking of Siloxane Polymers [J] . Zhuo Li, Kyoung-sik Moon, Ziyin Lin, Journal of Applied Polymer Science . 2014,第12期

机译：碳纳米管抑制硅氧烷聚合物的自由基交联
2. Control of intermolecular cross-linking reaction in free-radical cross-linking monovinyl/divinyl copolymerizations by the aid of amphiphilic nature of primary polymer chains and cross-link units with opposite polarities [J] . Doura M, Naka Y, Aota H, Macromolecules . 2005,第14期

机译：借助主聚合物链和具有相反极性的交联单元的两亲性质，控制自由基交联单乙烯基/二乙烯基共聚中的分子间交联反应
3. Regulated Dielectric Loss of Polymer Composites from Coating Carbon Nanotubes with a Cross-Linked Silsesquioxane Shell through Free-Radical Polymerization [J] . Da Sun, Zheng Zhou, Guang-Xin Chen ACS applied materials & interfaces . 2014,第21期

机译：通过自由基聚合通过交联倍半硅氧烷壳的涂层碳纳米管对聚合物复合材料介电损耗的调节
4. PROCESSING AND CHARACTERIZATION OF CARBON NANOTUBE/CORE SHELL SILOXANE MODIFIED HIGH TEMPERATURE BISMALEIMIDE POLYMERIC COMPOSITES [C] . Chukwuma E. Nweke, Shaik Zainuddin, Mahesh Hosur, SAMPE conference . 2016

机译：碳纳米管/核壳硅氧烷改性的高温双苯甲酰亚胺聚合物复合材料的制备与表征
5. Influence of Aspect Ratio and Surface Chemistry of Multi-walled Carbon Nanotubes on Structure and Properties of Multi-walled Carbon Nanotube/Polymer Composite Foams [D] . Chen, Limeng 2010

机译：多壁碳纳米管的长径比和表面化学性质对多壁碳纳米管/聚合物复合泡沫结构和性能的影响
6. bis-Nitrile and bis-Dialkylcyanamide Platinum(II) Complexes as Efficient Catalysts for Hydrosilylation Cross-Linking of Siloxane Polymers [O] . Regina M. Islamova, Mikhail V. Dobrynin, Daniil M. Ivanov, 2016

机译：双腈和双二烷基氰酰胺铂（II）配合物是硅氧烷聚合物氢化硅烷化交联的有效催化剂
7. Cross-linking of multiwalled carbon nanotubes with polymeric amines [O] . Youchun Zhang, Antonius A. Broekhuis, Marc C. A. Stuart, 2016

机译：多壁碳纳米管与聚合胺的交联

Carbon Nanotubes Inhibit the Free-Radical Cross-Linking of Siloxane Polymers

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