首页> 外文期刊>Journal of Applied Polymer Science >Cure Efficiency of Dodecyl Succinic Anhydride as a Cross-Linking Agent for Elastomer Blends Based on Epoxidized Natural Rubber
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Cure Efficiency of Dodecyl Succinic Anhydride as a Cross-Linking Agent for Elastomer Blends Based on Epoxidized Natural Rubber

机译:十二烷基琥珀酸酐作为基于环氧天然橡胶的弹性体混合物的交联剂的固化效率

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Blends of a highly epoxidized natural rubber (ENR50) with unmodified natural rubber (NR) and ethylene propylene elastomers (EPDM) were produced to evaluate the mixing and curing characteristics. Dodecyl succinic anhydride was used to cross-link the ENR50 component and the reactivity was assessed by monitoring the evolution of the torque in an oscillatory co-axial cylinder rheometer, as well as by DSC thermal analysis. A physical model was used to obtain a single parameter for the reactivity of the system, which corresponds to the rate constant for first order curing reactions. Although the blends were thermodynamically immiscible, displaying no significant change in T-g, the components were well dispersed at microscopic level. Better mechanical properties were obtained for blends with EPDM. (C) 2014 Wiley Periodicals, Inc.
机译:制备了高度环氧化的天然橡胶(ENR50)与未改性的天然橡胶(NR)和乙烯丙烯弹性体(EPDM)的共混物,以评估混合和固化特性。使用十二烷基琥珀酸酐使ENR50组分交联,并通过在振荡同轴圆柱流变仪中监测扭矩的变化以及通过DSC热分析来评估反应性。使用物理模型来获得系统反应性的单个参数,该参数对应于一级固化反应的速率常数。尽管共混物在热力学上是不混溶的,T-g没有显着变化,但组分在微观水平上分散良好。与EPDM共混可获得更好的机械性能。 (C)2014威利期刊公司

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