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Polyvinylbutyral-assisted synthesis and characterization of SnS mesoporous fibers via electrospinning process

机译:聚乙烯醇缩丁醛辅助纺丝工艺制备SnS介孔纤维

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摘要

Tin sulfide (SnS) has the potential to be used as a low-cost absorber material for applications in thin film photovoltaic solar cells. In this study, polyvinylbutyral/SnS (PVB/SnS) composite fibers were synthesized through a relatively simple electrospinning process. SnS mesoporous fibers were obtained from PVB/SnS composite fibers after sintering treatment at 500 degrees C for 1 h in N-2 atmosphere. The SnS mesoporous fibers were then characterized using X-ray powder diffraction, scanning electron microscopy, thermogravimetric analysis, and transmission electron microscopy. The optical properties of SnS mesoporous fibers were also recorded by UV-vis absorption spectroscopy. The results showed that the synthesized SnS mesoporous fibers exhibited a single phase, stoichiometric composition, with good crystallinity, a size ranging from 100 to 200 nm, and a band gap of 1.49 eV. The as-prepared SnS mesoporous fibers are thus a suitable material to achieve visible light absorption in a thin film solar cell. (C) 2015 Wiley Periodicals, Inc.
机译:硫化锡(SnS)具有用作薄膜光伏太阳能电池中低成本吸收材料的潜力。在这项研究中,聚乙烯醇缩丁醛/ SnS(PVB / SnS)复合纤维是通过相对简单的电纺丝工艺合成的。在N-2气氛中在500摄氏度下烧结处理1小时后,由PVB / SnS复合纤维获得SnS介孔纤维。然后使用X射线粉末衍射,扫描电子显微镜,热重分析和透射电子显微镜对SnS介孔纤维进行表征。 SnS中孔纤维的光学性质也通过紫外可见吸收光谱法记录。结果表明,合成的SnS介孔纤维表现出单相化学计量组成,具有良好的结晶度,尺寸范围为100至200nm,带隙为1.49eV。因此,所制备的SnS中孔纤维是在薄膜太阳能电池中实现可见光吸收的合适材料。 (C)2015年Wiley Periodicals,Inc.

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