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Polymeric membrane modification using SPEEK and bentonite for ultrafiltration of dairy wastewater

机译:使用SPEEK和膨润土进行聚合物膜改性以超滤乳品废水

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The different polymeric membrane materials were fabricated using modifiers such as sulfonated poly(ether ether ketone) (SPEEK) and bentonite for effective ultrafiltration of proteins from dairy effluent. Polyvinylidene fluoride (PVDF), polyethersulfone (PES), polyetherimide (PEI), polyamide-imides (PAI), cellulose acetate (CA), and polyphenylsulfone (PPSU) were selected for modification. Membrane morphology and functional group analysis were characterized using scanning electron microscopy (SEM) and Fourier transforms infrared spectroscopy (FTIR). Pure water permeability (64.66 x 10(-9) m/s kPa) was higher for the PES/SPEEK/bentonite membrane when compared with other polymeric membranes. Contact angle (54.05 degrees) value was lower for CA/SPEEK/bentonite membranes and which indicates that hydrophilicity has got enhanced. The membrane performance was tested using model dairy wastewater by ultrafiltration under longer run mode. Further it was evaluated using resistance in series model. This study infers that modification of membranes using charged SPEEK polymer and nanofiller as bentonite can be used to alleviate the fouling in the treatment of dairy wastewater. (c) 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41651.
机译:使用诸如磺化聚醚醚酮(SPEEK)和膨润土等改性剂制造不同的聚合物膜材料,以有效地从乳制品废水中超滤蛋白质。选择聚偏二氟乙烯(PVDF),聚醚砜(PES),聚醚酰亚胺(PEI),聚酰胺酰亚胺(PAI),醋酸纤维素(CA)和聚苯砜(PPSU)进行修饰。使用扫描电子显微镜(SEM)和傅里叶变换红外光谱(FTIR)表征膜的形态和官能团分析。与其他聚合物膜相比,PES / SPEEK /膨润土膜的纯净水渗透率(64.66 x 10(-9)m / s kPa)更高。 CA / SPEEK /膨润土膜的接触角(54.05度)值较低,这表明亲水性得到了增强。使用模型乳制品废水在更长的运行模式下通过超滤测试了膜的性能。此外,使用串联模型中的电阻对其进行了评估。这项研究推断,使用带电荷的SPEEK聚合物和纳米填料作为膨润土进行的膜改性可以减轻乳品废水的污染。 (c)2014 Wiley Periodicals,Inc. J. Appl。 Polym。科学2015,132,41651。

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