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Thermal and mechanical properties of liquid silicone rubber composites filled with functionalized graphene oxide

机译:官能化氧化石墨烯填充液态硅橡胶复合材料的热力学性能

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To improve the thermal and mechanical properties of liquid silicone rubber (LSR) for application, the graphene oxide (GO) was proposed to reinforce the LSR. The GO was functionalized with triethoxyvinylsilane (TEVS) by dehydration reaction to improve the dispersion and compatibility in the matrix. The structure of the functionalized graphene oxide (TEVS-GO) was evaluated by Thermogravimetric analysis (TGA), Fourier transform infrared (FTIR) spectra, X-ray diffraction (XRD), and energy dispersive X-ray spectroscopy (EDX). It was found that the TEVS was successfully grafted on the surface of GO. The TEVS-GO/LSR composites were prepared via in situ polymerization. The structure of the composites was verified by FTIR, XRD, and scanning electron microscopy (SEM). The thermal properties of the composites were characterized by TGA and thermal conductivity. The results showed that the 10% weight loss temperature (T-10) increased 16.0 degrees C with only 0.3 wt % addition of TEVS-GO and the thermal conductivity possessed a two-fold increase, compared to the pure LSR. Furthermore, the mechanical properties were studied and results revealed that the TEVS-GO/LSR composites with 0.3 wt % TEVS-GO displayed a 2.3-fold increase in tensile strength, a 2.79-fold enhancement in tear strength, and a 1.97-fold reinforcement in shear strength compared with the neat LSR. (c) 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42582.
机译:为了改善液态硅橡胶(LSR)的热学和机械性能,提出了氧化石墨烯(GO)来增强LSR。通过三乙氧基乙烯基硅烷(TEVS)通过脱水反应将GO功能化,以改善在基质中的分散性和相容性。通过热重分析(TGA),傅立叶变换红外(FTIR)光谱,X射线衍射(XRD)和能量色散X射线光谱(EDX)对功能化氧化石墨烯(TEVS-GO)的结构进行了评估。发现TEVS成功地接枝在GO表面上。通过原位聚合制备TEVS-GO / LSR复合材料。通过FTIR,XRD和扫描电子显微镜(SEM)验证了复合材料的结构。通过TGA和热导率表征了复合材料的热性能。结果表明,与纯LSR相比,仅添加0.3 wt%的TEVS-GO,失重10%的温度(T-10)升高了16.0℃,并且热导率增加了两倍。此外,对机械性能进行了研究,结果表明,TEVS-GO含量为0.3 wt%的TEVS-GO / LSR复合材料的拉伸强度提高了2.3倍,撕裂强度提高了2.79倍,增强强度为1.97倍与纯LSR相比,其剪切强度更高。 (c)2015 Wiley Periodicals,Inc. J. Appl。 Polym。科学2015,132,42582。

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