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Oil-absorbent polyurethane sponge coated with KH-570-modified graphene

机译:涂有KH-570改性石墨烯的吸油性聚氨酯海绵

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Polyurethane (PU) sponge has become a preferred oil adsorbent in recent oil-spill accidents. To make the sponge superhydrophobicand superoleophilic, this study used graphene (GN), which was modified with gamma-methacryloxypropyl trimethoxy silane (KH-570), to coat the PU sponge (called the KH-GN sponge). This study showed the best loading capacity (11.96%) of the KH-570-modified GN on the sponge. The contact angles of the KH-GN PU sponge were 161 degrees for water and 0 degrees for soybean, diesel, and pumping oil. It had good selectivity for oil over water, and the KH-GN sponge achieved adsorption equilibrium within a few seconds. The absorption capability of the KH-GN sponge was up to 39 times greater, Additionally, the KH-GN sponge could be reused for oil-water separation for more than 120 cycles without losing its superhydrophobic and superoleophilic properties. Therefore the sponge prepared in this study could be a desirable material for the cleanup of oil spills. 2015 Wiley Periodicals, Inc.
机译:在最近的溢油事故中,聚氨酯海绵已成为首选的吸油剂。为了使海绵具有超疏水性和超亲油性,本研究使用了石墨烯(GN),并用γ-甲基丙烯酰氧基丙基三甲氧基硅烷(KH-570)对其进行了改性,以涂覆PU海绵(称为KH-GN海绵)。这项研究表明,KH-570改性GN在海绵上的最佳负载能力(11.96%)。 KH-GN PU海绵的水接触角为161度,大豆,柴油和抽油机油的接触角为0度。它对水的油具有很好的选择性,并且KH-GN海绵在几秒钟内达到了吸附平衡。 KH-GN海绵的吸收能力高达39倍,此外,KH-GN海绵可重复用于油水分离超过120个循环,而不会失去其超疏水和超亲油性。因此,本研究中准备的海绵可能是清除溢油的理想材料。 2015年Wiley Periodicals,Inc.

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