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Epoxy shape-memory polymer reinforced by thermally reduced graphite oxide: Influence of processing techniques

机译:热还原氧化石墨增强的环氧形状记忆聚合物:加工技术的影响

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摘要

In this article, epoxy shape-memory polymer (ESMP) reinforced with 1 wt % thermally reduced graphite oxide (TrGO) was fabricated by solution blending and three-roll mill (TRM) mixing, respectively. Both blending techniques allowed a uniform TrGO dispersion in ESMP matrix, and the TRM mixing lead to an exfoliation of the TrGO worms. Compared with pristine ESMP, the TrGO/ESMP composites showed 36.4-41.1% increase in Young's modulus and 38.1-44.1% improvement in tensile strength. The TrGO/ESMP composite fabricated by TRM mixing had a T-5% (the temperature where the material lost 5% of its initial weight) 16.4 degrees C higher than pure ESMP. Compared with pure ESMP, a significant improvement of recovery force by 84.4% and 311.1% was obtained by TrGO/ESMP composite fabricated by solution blending and TRM mixing, respectively. (c) 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42502.
机译:在本文中,分别通过溶液共混和三辊磨(TRM)混合制备了以1 wt%的热还原氧化石墨(TrGO)增强的环氧形状记忆聚合物(ESMP)。两种混合技术均允许TrGO在ESMP基质中均匀分散,并且TRM混合导致TrGO蠕虫剥落。与原始ESMP相比,TrGO / ESMP复合材料的杨氏模量增加了36.4-41.1%,拉伸强度提高了38.1-44.1%。通过TRM混合制造的TrGO / ESMP复合材料的T-5%(材料失去其初始重量5%的温度)比纯ESMP高16.4摄氏度。与纯ESMP相比,通过溶液共混和TRM混合制备的TrGO / ESMP复合材料的恢复力分别显着提高了84.4%和311.1%。 (c)2015 Wiley Periodicals,Inc. J. Appl。 Polym。科学2015,132,42502。

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