首页> 外文期刊>Journal of Applied Polymer Science >Structural aspects of mechanical properties of iPP-based composites. I. Composite iPP fibers with VGCF nanofiller
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Structural aspects of mechanical properties of iPP-based composites. I. Composite iPP fibers with VGCF nanofiller

机译:iPP基复合材料的机械性能的结构方面。 I.带有VGCF纳米填料的复合iPP纤维

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Nanocomposite fibers consisting of isotactic polypropylene (iPP) as a matrix filled with vapor grown carbon nanofibers (VGCF) have been prepared and their fine crystalline structure and mechanical properties characterized. The obtained results point out that the VGCF oriented along the fiber extrusion direction induce crystallization in the surrounding iPP matrix in a special way leading to the formation of oriented iPP a-transcrystallite layers. The VGCF content and the draw ratio (DR) affect the textural properties of the composite material and lead to the formation of an anisotropic structure. The improvements of the mechanical properties of the composite fibers in both undrawn and drawn states are attributed to the VGCF aligning effect during extrusion, which produces highly oriented iPP crystalline structure, rather than to the reinforcing effect of the nanofibers. A new detailed scheme explaining the changes in tensile strength from the structural point of view is proposed. (C) 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41865.
机译:已经制备了由等规聚丙烯(iPP)组成的纳米复合纤维,并填充了气相生长的碳纳米纤维(VGCF),并表征了其精细的晶体结构和机械性能。所得结果指出,沿纤维挤出方向取向的VGCF以特殊的方式在周围的iPP基体中引起结晶,从而导致取向的iPPα-透晶层的形成。 VGCF含量和拉伸比(DR)影响复合材料的质构特性,并导致各向异性结构的形成。复合纤维在未拉伸和拉伸状态下的机械性能的改善归因于挤出过程中的VGCF对准效应,该取向会产生高度取向的iPP晶体结构,而不是纳米纤维的增强作用。提出了一种新的详细方案,从结构的角度解释了抗张强度的变化。 (C)2015 Wiley Periodicals,Inc. J. Appl。 Polym。科学2015,132,41865。

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