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Carbon nanotubes-polymer nanocomposites for controlled heating materials

机译:碳纳米管-聚合物纳米复合材料,用于受控加热材料

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Nanocomposites of modified carbon nanotubes (CNT) and either polyurethane (PU), poly(vinyl acetate) (PVAc), or silicone materials were synthetized and characterized for thermal mat application. The obtained results revealed that the polymer used as a matrix had an impact on the electrical resistance of the mats. The lowest results of 32 of resistance was registered with silicone-based mats containing 5 wt % of CNT. For the same CNT content the mats based on PVAc and PU displayed values of 55 and 60 , respectively. The low resistance properties of silicone-based materials were due principally to the good compatibility of both polymer and functionalized CNT. Because of the low resistance values, this mat was subjected to thermovision analysis revealing that the samples reached temperature of about 60 degrees C in 9 min and 70 degrees C after 27 min of 27 V of applied potential. The results showed an almost uniform temperature distribution in the samples' surface with some high and low temperature spots, which were attributed to nonuniform distribution of CNT in the polymer matrix. In summary, all the obtained results confirm that silicone-CNT are very promising materials that can be used as low-voltage heating mats. (c) 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 44194.
机译:合成了改性碳纳米管(CNT)和聚氨酯(PU),聚醋酸乙烯酯(PVAc)或有机硅材料的纳米复合材料,并进行了热垫应用的表征。获得的结果表明,用作基质的聚合物对垫的电阻有影响。电阻为32的最低结果记录在含有5%CNT的有机硅基垫上。对于相同的CNT含量,基于PVAc和PU的垫子分别显示值55和60。有机硅基材料的低电阻性能主要归因于聚合物和官能化CNT的良好相容性。由于电阻值低,因此对该垫进行了热像分析,结果表明样品在施加电压27 V的27分钟后的9分钟内达到了约60摄氏度,在70摄氏度下达到了约70摄氏度。结果表明,样品表面的温度分布几乎均匀,并带有一些高温点和低温点,这归因于CNT在聚合物基质中的分布不均匀。总之,所有获得的结果证实,有机硅-CNT是非常有前途的材料,可以用作低压加热垫。 (c)2016 Wiley Periodicals,Inc. J. Appl。 Polym。科学2016,133,44194。

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