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Phosphorous, nitrogen co-doped carbon from spent coffee grounds for fuel cell applications

机译:来自废咖啡渣的磷,氮共掺杂碳,用于燃料电池应用

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Spent coffee grounds, which represents the vast solid residual matter generated from consumed coffee beans, requires proper reutilization. This work represents the production of an alternate material from spent coffee grounds to replace expensive metal based catalysts currently used as electrodes in fuel cells. A novel microwave assisted technique which is easy, rapid, and economical is utilized for the synthesis of Phosphorous, Nitrogen co-doped carbon (PNDC) from spent coffee grounds and ammonium polyphosphate. SEM analysis revealed that PNDC is composed of distinct, spherical shaped particles. PNDC has a BET surface area of approximate to 507 m(2) g(-1) and is predominantly mesoporous. XPS reveals that PNDC contains about 1.90% N and 3.02% P besides C and O. PNDC exhibits good O-2 reduction response in 0.1M KOH, which was found to be comparable to that of 20% Pt/C. (c) 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41948.
机译:用过的咖啡渣表示从消耗的咖啡豆中产生的大量固体残留物,需要适当地重新利用。这项工作代表了用废咖啡渣生产替代材料来替代目前用作燃料电池中电极的昂贵的金属基催化剂。一种简便,快速且经济的新型微波辅助技术可用于从废咖啡渣和聚磷酸铵合成磷,氮共掺杂碳(PNDC)。 SEM分析表明PNDC由不同的球形颗粒组成。 PNDC的BET表面积大约为507 m(2)g(-1),并且主要是中孔的。 XPS显示,PNDC除含有C和O之外,还含有约1.90%的N和3.02%的P。PNDC在0.1M KOH中表现出良好的O-2还原响应,与20%Pt / C相当。 (c)2015 Wiley Periodicals,Inc. J. Appl。 Polym。科学2015,132,41948。

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