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Preparation and application of tectoridin-imprinted magnetite nanoparticles

机译:胸苷素印迹磁铁矿纳米粒子的制备及应用

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In this work, the tectoridin-imprinted magnetite nanoparticles (TIMNPs) were firstly prepared by using tectoridin as template molecule, methacrylic acid as functional monomer, styrene as crosslinking agent, and superparamagnetic Fe3O4 particles as magnetic component. TIMNPs with a size of about 161 nm were characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), Fourier transform infrared (FT-IR), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and thermogravimetric analysis (TGA). Rebinding experiments were carried out to determine the specific binding properties and adsorption selectivity. The maximum number of binding sites was 69.58 lmol/g and there was only one kind of binding sites existed in TIMNPs. The relative separation factors for tectoridin with its analogues such as baicalin and atenolol were 2.63 and 2.66, respectively. The results indicated that the synthesized TIMNPs had excellent saturation magnetization, binding capacity, and absorption selectivity. TIMNPs could be one of the most promising candidates for tectoridin extraction. (C) 2016 Wiley Periodicals, Inc.
机译:在本文中,首先以Tectoridin为模板分子,甲基丙烯酸为功能单体,苯乙烯为交联剂,超顺磁性Fe 3 O 4颗粒为磁性组分,制备了含有鸟苷肽的磁铁矿纳米颗粒(TIMNPs)。通过扫描电子显微镜(SEM),透射电子显微镜(TEM),傅立叶变换红外(FT-IR),X射线衍射(XRD),振动样品磁力计(VSM)和热重分析(TGA)。进行重新结合实验以确定特异性结合性质和吸附选择性。结合位点的最大数量为69.58 lmol / g,TIMNPs中仅存在一种结合位点。替考替丁及其类似物如黄ical苷和阿替洛尔的相对分离因子分别为2.63和2.66。结果表明,合成的TIMNPs具有优异的饱和磁化强度,结合能力和吸收选择性。 TIMNPs可能是最有前途的替考丁提取物之一。 (C)2016威利期刊公司

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