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首页> 外文期刊>Journal of Applied Polymer Science >Diluent selection for Nylon 11 and Nylon 12 thermally induced phase separation systems
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Diluent selection for Nylon 11 and Nylon 12 thermally induced phase separation systems

机译：尼龙11和尼龙12热诱导相分离系统的稀释剂选择

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摘要

Nylon 11 and Nylon 12 are commercially important polymers due to their unique combination of mechanical strength, chemical resistance, and processability. Products have been prepared from these polymers via thermally induced phase separation (TIPS) for many years. Nevertheless, known diluents for Nylon 11 and 12 pose specific processing problems, and it would be desirable to find a diluent that allows low processing temperatures, has a high flash point, is inexpensive, and exhibits low toxicity. This work investigated a variety of alternative diluents not previously documented in the literature. A fundamental study was also performed to determine which factors are important in selecting a diluent for preparing Nylon liquid-liquid TIPS membranes. The information gathered in this study, including phase diagrams for all feasible systems investigated, will be important in shaping future formulation work for Nylon use in microporous membranes. (c) 2015 Wiley Periodicals, Inc.
机译：尼龙11和尼龙12由于其机械强度，耐化学性和可加工性的独特组合而成为商业上重要的聚合物。多年来，已经通过热诱导相分离（TIPS）由这些聚合物制备了产品。然而，已知的尼龙11和尼龙12的稀释剂存在特定的加工问题，并且期望找到一种允许低加工温度，具有高闪点，便宜且显示低毒性的稀释剂。这项工作研究了以前文献中未记载的多种替代稀释剂。还进行了基础研究，以确定哪些因素对选择用于制备尼龙液-液TIPS膜的稀释剂很重要。这项研究中收集到的信息，包括所研究的所有可行系统的相图，对于塑造未来在微孔膜中使用尼龙的配方工作至关重要。 （c）2015年威利期刊有限公司

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