• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Journal of Applied Polymer Science >Oxime crosslinked polymer networks: Is every reversible covalent bond suitable to create self-healing polymers?
【24h】

Oxime crosslinked polymer networks: Is every reversible covalent bond suitable to create self-healing polymers?

机译：肟交联的聚合物网络：是否每个可逆的共价键都适合产生自修复聚合物？

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

The incorporation of reversible covalent bonds into polymeric materials offers the possibility to generate polymers with self-healing ability. For this purpose, three new oxime crosslinkers are synthesized and crosslinked by the copolymerization with different commercially available methacrylates via a photo-polymerization process. These crosslinked materials are investigated regarding a potential self-healing behavior. Moreover, the influence of different additives (polymerizable acids, photo acids, and acid developers) to enable self-healing is studied in detail. Thereby, the limit of self-healing based on reversible covalent bonds is reached in these materials. Due to the high stability of the oxime bonds in bulk materials no exchange reactions as well as no self-healing behavior could be observed. (C) 2016 Wiley Periodicals, Inc.
机译：将可逆共价键结合到聚合物材料中提供了产生具有自我修复能力的聚合物的可能性。为此，通过光聚合方法，通过与不同的市售甲基丙烯酸酯共聚，合成并交联了三种新的肟交联剂。研究了这些交联材料的潜在自我修复行为。此外，详细研究了不同添加剂（可聚合酸，光酸和酸显影剂）对实现自我修复的影响。因此，在这些材料中达到了基于可逆共价键的自我修复的极限。由于本体材料中肟键的高稳定性，因此未观察到交换反应以及自愈行为。 （C）2016威利期刊公司

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号