Spectroscopic study of lanthanide (III) complexes with chosen aminoacids and hydroxyacids in solution

Z.Hnatejko; S.Lis

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Spectroscopic study of lanthanide (III) complexes with chosen aminoacids and hydroxyacids in solution

机译：镧系元素（III）与选定氨基酸和羟酸配合物在溶液中的光谱研究

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Luminescence spectra and lifetime of Eu(III) andTb(III) ions in complexes with glycine (AAA), glycolic acid (GA),aspartic acid (ASP) and manic acid (MA) were studied. The effectof the amino-NH_2 and hydroxyl-OH groups on the intensity andlifetime of the lanthanides luminescence were examined.Hydration number for Eu(III) in the systems studied indicated theinvolvement of carboxyl and hydroxyl groups as well as donornitrogen atoms in the coordination. The phenomenon of Gd(III)ion emission quenching was analyzed and quantitatively describedby determination of the quenching constant K_(SV).

机译：研究了与甘氨酸（AAA），乙醇酸（GA），天冬氨酸（ASP）和甘露酸（MA）配合物中Eu（III）和Tb（III）离子的发光光谱和寿命。考察了氨基-NH_2和羟基-OH基团对镧系元素发光强度和寿命的影响。研究体系中Eu（III）的水合数表明了羧基，羟基以及供体氮原子的参与。通过确定猝灭常数K_（SV），分析并定量描述了Gd（III）离子发射猝灭现象。

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《Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics》 |2000年第0期|共7页
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Z.Hnatejko; S.Lis;
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Aminoacid and hydroxyacid complexes; Energy transfer; Hydration; Ln(III) complexes; Luminescence;

机译：氨基酸和羟基酸配合物;能量转移;水合;Ln（III）配合物;发光;

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1. Spectroscopic study of lanthanide (III) complexes with chosen aminoacids and hydroxyacids in solution [J] . Z.Hnatejko, S.Lis Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2000,第0期

机译：镧系元素（III）与选定氨基酸和羟酸配合物在溶液中的光谱研究
2. Structural and spectroscopic studies of [bis(picrato)(pentaethylene glycol)lanthanide(III)] picrate complexes with Ln(III) = Sm, Dy and Ho [J] . Muhammad I. Saleh, Eny Kusrini, Rohana Adnan, Journal of Molecular Structure . 2007,第1a3期

机译：Ln（III）= Sm，Dy和Ho的[双（吡啶）（五乙二醇）镧系元素（III）]苦味酸盐配合物的结构和光谱研究
3. TRLIFS study of Eu(III) spectroscopic properties to obtain structural and thermodynamic informations on lanthanide-malonamide complexes in the Eu(III)/NaNO3/TetraEthylMalonAmide system [J] . Couston L, Charbonnel MC, Flandin JL, Radiochimica Acta: International Journal for Chemical Aspects of Nuclear Science and Technology . 2004,第7期

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4. Solution Structure Trumps Energy - Determining Factors for the Luminescent Properties of Multimetallic Kinetically Inert Lanthanide(III) Complexes [C] . Thomas Just Sorensen Rare Earth Research Conference . 2019

机译：解决方案结构胜过多金属动态惰性镧系元素（III）复合物的发光性能的能量确定因素
5. I. THE ELECTROCHEMISTRY OF NITRIC OXIDE AND A NITROUS ACID AT A MERCURY ELECTRODE IN AQUEOUS SOLUTIONS. II. ELECTROCHEMISTRY AND HYDROLYSIS KINETICS OF THE 2,2'-BIPYRIDINE COMPLEXES OF IRON(III) AND IRON(II); ELECTROCHEMICAL KINETIC PARAMETERS FOR SEVERAL IRON COMPLEXES. III. PROTON NUCLEAR MAGNETIC RESONANCE STUDIES OF URANIUM(IV)-ETHYLENE DIAMINETETRAACETIC ACID COMPLEXES IN AQUEOUS (DEUTERIUM-OXIDE) SOLUTIONS. [D] . EHMAN, DEWAYNE LEE. 1969

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6. Thermodynamic and Spectroscopic Studies of the Complexes Formed in Tartaric Acid and Lanthanide(III) Ions Binary Systems [O] . Michal Zabiszak, Martyna Nowak, Zbigniew Hnatejko, 2020

机译：酒石酸和镧系元素离子二元体系形成的配合物的热力学和光谱研究
7. Solvent Extraction Study of Trivalent Actinide and Lanthanide Complexes in Aqueous Solutions. IV. Thiocyanate Complexes of La(III), Eu(III), Lu(III), and Am(III) in 5 M Na(ClO4) Solutions at 25 degrees C. [O] . Tatsuya Sekine, Sigurd Joys, Nils Jakob Gröndahl, 1965

机译：三价神经肌细胞和镧系元素水溶液中的溶剂提取研究。 IV。硫氰酸酯络合物的La（III），EU（III），Lu（III）和Am（III）的含量在25摄氏度下为5M Na（CLO 4）溶液。

Spectroscopic study of lanthanide (III) complexes with chosen aminoacids and hydroxyacids in solution

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