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The phase diagram of the Ba-Ge system

机译:Ba-Ge系统的相图

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摘要

The phase diagram of the Ba-Ge system has been revised, in the composition range 0-75 at. percent Ge, from a thermal point of view, resulting substantially different from that previously reported in Massalski collection. The existence and composition of the following compounds are confirmed: Ba_2Ge, Ba_5Ge_3, BaGe, dimorphic Ba_5Ge_4BaGe_2, Ba_6Ge_(25) and Ba_8Ge_(43). Save for Ba_2Ge, BaGe and BaGe_2, forming congruently, all other phases melt incongruently. Four eutectic points occur at 7.5,42.5, 56.0 and 82.5 at. percent Ge, respectively.
机译:Ba-Ge体系的相图已被修改,其组成范围为0-75 at。从热学的角度来看,Ge的百分含量与先前Massalski收集的结果大不相同。确认以下化合物的存在和组成:Ba_2Ge,Ba_5Ge_3,BaGe,双晶Ba_5Ge_4BaGe_2,Ba_6Ge_(25)和Ba_8Ge_(43)。除Ba_2Ge,BaGe和BaGe_2以外,其他所有相均完全熔融形成。在7.5、42.5、56.0和82.5 at处出现四个共晶点。百分比锗。

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