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首页> 外文期刊>Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics >Structural archetypes in nickel(II) hybrid vanadates. Towards a directed hydrothermal synthesis
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Structural archetypes in nickel(II) hybrid vanadates. Towards a directed hydrothermal synthesis

机译:镍(II)混合钒酸盐的结构原型。进行定向水热合成

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In the present work, we relate the modifications of the initial synthesis parameters (pH value, stoi-chiometry and concentration) with the different structural archetypes obtained in the {Ni/Bpy/VO} and {Ni/Bpe/VO} systems (4,4'-bipyridine (Bpy), 1,2-di(4-pyridyl) ethylene (Bpe)). The vanadium coordination is partially controlled by the hydrothermal synthesis conditions, and the final crystal structures depend on the synergetic interaction between the metal-organic subnets and the vanadium oxide subunits.
机译:在目前的工作中,我们将初始合成参数(pH值,化学计量和浓度)的修改与在{Ni / Bpy / VO}和{Ni / Bpe / VO}系统中获得的不同结构原型相关联(4 ,4'-联吡啶(Bpy),1,2-二(4-吡啶基)乙烯(Bpe))。钒的配位部分受水热合成条件控制,最终的晶体结构取决于金属-有机子网与氧化钒亚单元之间的协同相互作用。

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