A revision of the central part of the Cr-Ge phase diagram

Isabella Jandl; Klaus W. Richter

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A revision of the central part of the Cr-Ge phase diagram

机译：修订Cr-Ge相图的中心部分

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摘要

The central part of the Cr-Ge phase diagram was re-investigated using powder-X-ray diffraction (XRD),differential thermal analysis (DTA) and chemical vapour transport (CVT). It was found that the phase Cr_5Ge_3 (Si_3W_5-type structure) does not show a polymorphic transformation as reported previously, but rather undergoes a eutectoidic decomposition reaction Cr_5Ge_3 = Cr_3Ge + Cr_(11)Ge_8 at T = 996℃. A revised version of the corresponding region of the phase diagram is given.

机译：Cr-Ge相图的中心部分使用粉末X射线衍射（XRD），差热分析（DTA）和化学气相传输（CVT）进行了重新研究。结果发现，相Cr_5Ge_3（Si_3W_5型结构）没有显示出先前报道的多晶相转变，而是在T = 996℃下发生了共晶分解反应Cr_5Ge_3 = Cr_3Ge + Cr_（11）Ge_8。给出了相图相应区域的修订版。

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来源
《Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics》 |2010年第1期|共3页
作者
Isabella Jandl; Klaus W. Richter;
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正文语种 eng
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关键词
Cr-Ge system; Phase diagram; Cr_5Ge_3;

机译：Cr-Ge体系;相图;Cr_5Ge_3;

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A revision of the central part of the Cr-Ge phase diagram

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