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首页> 外文期刊>Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics >Magnetic properties of the 1/1 approximant Ag_(42)In_(42)Gd_(16) to the icosahedral quasicrystal Ag-In-Gd
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Magnetic properties of the 1/1 approximant Ag_(42)In_(42)Gd_(16) to the icosahedral quasicrystal Ag-In-Gd

机译:接近二十面体准晶体Ag-In-Gd的1/1近似Ag_(42)In_(42)Gd_(16)的磁性

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摘要

The structural, magnetic, and ~(155)Gd Mossbauer spectral properties of the 1/1 approximant Ag_(42)In_(42)Gd_(16) to an icosahedral quasicrystal Ag-In-Gd are reported. Based on dc magnetic susceptibility measurements, it is shown that the studied compound develops no long-range magnetic order in the temperature range 1.8-300 K. The dc zero-field-cooled and field-cooled susceptibility data indicate that the 1/1 approximant Ag_(42)In_(42)Gd_(16) is a spin glasss with freezing temperature T_f=3.6(1)K. This is further confirmed by the analysis of the frequency dependence of T_f using the Vogel-Fulcher law and the dynamic scaling behavior near T_f. It is argued that the spin freezing process is a true equilibrium phase transition rather than a nonequilibrium phenomenon. The large frustration parameter of the studied compound indicates that it belongs to a category of strongly geometrically frustrated magnets. The ~(155)Gd Mossbauer spectra of the 1/1 approximant Ag_(42)In_(42)Gd_(16) confirm that the Gd spins are frozen at 1.5 K and are fluctuating at 4.6 K. The Debye temperature of the 1/1 approximant Ag_(42)In_(42)Gd_(16) is 200(1)K.
机译:报道了与二十面体准晶体Ag-In-Gd的1/1近似的Ag_(42)In_(42)Gd_(16)的结构,磁性和〜(155)Gd Mossbauer光谱性质。根据直流磁化率的测量结果表明,所研究的化合物在1.8-300 K的温度范围内没有长程磁序。直流零场冷和场冷磁化率数据表明,1/1近似值Ag_(42)In_(42)Gd_(16)是冻结温度T_f = 3.6(1)K的旋转玻璃。通过使用Vogel-Fulcher定律分析T_f的频率依赖性以及T_f附近的动态缩放行为,可以进一步证实这一点。认为自旋冻结过程是真正的平衡相变,而不是非平衡现象。研究化合物的大挫折参数表明它属于强几何挫折磁体类别。 1/1近似值Ag_(42)In_(42)Gd_(16)的〜(155)Gd Mossbauer光谱证实,Gd自旋冻结在1.5 K,并在4.6 K波动。1/的德拜温度。 1个近似值Ag_(42)In_(42)Gd_(16)为200(1)K。

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