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首页> 外文期刊>Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics >Enhanced photoluminescence of GdPO_4:Tb~(3+) under VUV excitation by controlling ZnO content and annealing temperature
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Enhanced photoluminescence of GdPO_4:Tb~(3+) under VUV excitation by controlling ZnO content and annealing temperature

机译:通过控制ZnO含量和退火温度,在VUV激发下增强GdPO_4:Tb〜(3+)的光致发光

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摘要

High-quality Zn-free and added GdPO_4:Tb~3 green phosphors, i.e., fine size as well as smooth and spherical morphologies, were synthesized by ultrasonic spray pyrolysis. The influence of Zn~(2+) content and annealing temperature on the photoluminescence properties of the GdPO_4:Tb~3 phosphors annealed at 800-1100°C was investigated. The addition of Zn~(2+) for Gd~(3+) was highly effective for improving the photoluminescence properties of GdPO_4:Tb~3. The Zn added GdPO_4:Tb~3 phosphors with Zn/Gd = 0.045/0.805 showed the strongest emission of the prepared phosphors. The emission intensity at 544 nm for the GdPO_4:Tb~3 phosphors with Zn/Gd = 0.045/0.805 annealed at 900 °C was 496% stronger than that at 800 ° C.
机译:通过超声喷雾热解合成了高质量的无锌并添加了GdPO_4:Tb〜3的绿色荧光粉,即具有细小尺寸以及光滑和球形的形态。研究了Zn〜(2+)含量和退火温度对在800〜1100℃退火的GdPO_4:Tb〜3荧光粉的光致发光性能的影响。 Zn〜(2+)对Gd〜(3+)的添加对提高GdPO_4:Tb〜3的光致发光性能非常有效。 Zn / Gd = 0.045 / 0.805的添加Zn的GdPO_4:Tb〜3磷光体显示出所制备磷光体的最强发射。在900°C退火的Zn / Gd = 0.045 / 0.805的GdPO_4:Tb〜3磷光体在544 nm处的发射强度比在800°C时强496%。

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