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DC magnetization investigations in Ti_(1-x)Mn_xO_2 nanocrystalline powder

机译:Ti_(1-x)Mn_xO_2纳米晶粉末的直流磁化研究

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摘要

In the present paper, DC magnetization investigation on the insulating nanocrystalline powder samples of Ti_(1-x)Mn_xO_2 (x = 0,0.05,0.10, and 0.15) prepared by simple chemical route is reported. Structural measurements revealed phase pure anatase structure of TiO_2 when x < = 0.05 and a mixture of anatase and rutile TiO_2 along with the signature of Mn_3O_4 phase for x > = 0.05. Magnetic measurements exhibited the presence of ferromagnetic ordering at room temperature in samples having either small fraction of Mn or no Mn at all. This ferromagnetic signature is accompanied with paramagnetic contribution which is found to dominate with increase in Mn concentration.
机译:本文报道了通过简单化学路线制备的Ti_(1-x)Mn_xO_2(x = 0,0.05,0.10,和0.15)绝缘纳米晶粉末样品的直流磁化研究。结构测量表明,当x <= 0.05时,TiO_2具有纯的锐钛矿相结构,而对于x> = 0.05,则具有锐钛矿和金红石TiO_2的混合物以及Mn_3O_4相的特征。磁性测量结果显示,在室温下,具有少量Mn或完全不含Mn的样品中存在铁磁有序。该铁磁特征伴随着顺磁贡献,发现其随Mn浓度的增加而占主导地位。

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