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首页> 外文期刊>Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics >Characterization of sol-gel synthesised lead-free (1 -x)Na_(0.5)Bi_(0.5)TiO_3-xBaTiO_3 -based ceramics
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Characterization of sol-gel synthesised lead-free (1 -x)Na_(0.5)Bi_(0.5)TiO_3-xBaTiO_3 -based ceramics

机译:溶胶-凝胶法合成无铅(1-x)Na_(0.5)Bi_(0.5)TiO_3-xBaTiO_3基陶瓷的表征

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摘要

The crystal structure, microstructure, dielectric and ferroelectric properties of (1 -x)Na_(0.5)Bi_(0.5)TiO_3-xBaTiO_3 ceramics with x = 0, 0.03, 0.05, 0.07 and 0.1 are investigated. A structural variation according to the system composition was investigated by X-ray diffraction (XRD) analyses. The results revealed that the synthesis temperature for pure perovskite phase powder prepared by the present sol-gel process is much lower (800 °C), and a rhombohedral-tetragonal morphotropic phase boundary (MPB) is found for x = 0.07 composition which showing the highest remanent polarization value and the smallest coercive field.
机译:研究了x = 0、0.03、0.05、0.07和0.1的(1-x)Na_(0.5)Bi_(0.5)TiO_3-xBaTiO_3陶瓷的晶体结构,微观结构,介电和铁电性能。通过X射线衍射(XRD)分析研究了根据系统组成的结构变化。结果表明,通过本溶胶-凝胶法制备的纯钙钛矿相粉末的合成温度要低得多(800°C),并且对于x = 0.07的组成,发现了菱面体-四方晶相相界(MPB),表明剩余极化值最高,矫顽场最小。

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