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The high capacity and controllable hydrolysis rate of Mg_3La hydride

机译:Mg_3La氢化物的高容量和可控制的水解速率

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摘要

This paper reports the synthesis of Mg_3La alloys with different hydrogenation degree through controlling the hydrogen amount introduced and reveals the hydrogenation mechanism. The hydrolysis rate and hydrogen yield of Mg_3La hydride could be controllable through adjusting the ratio of LaH_3 to Mg or MgH_2. The fully hydrogenated Mg_3La alloy can generate 873.24 ml g~(-1) in 66 min (7.80 wt.%). The results show that the hydrolysis performance of MgH_2 in Mg_3La hydrides could be significantly accelerated by LaH_3 while that of Mg was affected limitedly by LaH_3.
机译:通过控制氢的引入量,报道了不同氢化度的Mg_3La合金的合成,揭示了氢化机理。通过调节LaH_3与Mg或MgH_2的比例可以控制Mg_3La氢化物的水解速率和氢产率。完全氢化的Mg_3La合金可在66分钟内产生873.24 ml g〜(-1)(7.80 wt。%)。结果表明,LaH_3可以显着促进Mg_3La氢化物中MgH_2的水解性能,而LaH_3可以有限地影响Mg的水解性能。

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