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Experimental and theoretical studies of optical and nonlinear optical properties for MnTeMoO6 crystal

机译:MnTeMoO6晶体的光学和非线性光学性质的实验和理论研究

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MnTeMoO6 crystal was obtained by top-seeded solution growth method. Optical and nonlinear optical properties of MnTeMoO6 crystal were measured. Band structures, DOS, optical properties of MnTeMoO6 were calculated. Both calculated and experiment results of the optical properties show that a transitional absorption band is exhibited in MnTeMoO6 crystal. Second harmonic generation measurements show that the SHG response with fundamental wavelength 1.06 mm decreases to a quarter of that with fundamental wavelength 2.05 mm. The transitional absorption band has a great effect on the nonlinear optical property of MnTeMoO6 crystal. The formation of the transitional absorption band in MnTeMoO6 crystal would be attributed to the internal transitions of transition-meta ions with incomplete electron shells (Mn2+ 3d(3)4s(2)). In addition, the transitional absorption band plays an important role in the coloration of MnTeMoO6 crystal, and the crystal can be made into selective optical oscillators and laser wavelength recognizing device by utilizing the characteristic of the transitional absorption band. (C) 2015 Elsevier B.V. All rights reserved.
机译:MnTeMoO6晶体是通过顶晶溶液生长法获得的。测量了MnTeMoO6晶体的光学和非线性光学性质。计算了MnTeMoO6的能带结构,DOS,光学性质。光学性能的计算和实验结果均表明,MnTeMoO6晶体具有过渡吸收带。二次谐波产生的测量结果表明,基波波长为1.06 mm的SHG响应降低到基波波长为2.05 mm的四分之一。过渡吸收带对MnTeMoO6晶体的非线性光学性质有很大影响。 MnTeMoO6晶体中过渡吸收带的形成将归因于具有不完整电子壳(Mn2 + 3d(3)4s(2))的过渡金属离子的内部过渡。另外,过渡吸收带在MnTeMoO6晶体的着色中起重要作用,并且可以利用过渡吸收带的特性将该晶体制成选择性光学振荡器和激光波长识别装置。 (C)2015 Elsevier B.V.保留所有权利。

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