Calorimetric study of peculiar hydrogenation behavior of nanocrystalline TiFe

Berdonosova Elena A.; Klyamkin Semen N.; Zadorozhnyy Vladislav Yu.; Zadorozhnyy Mikhail Yu.; Geodakian Karen V.; Gorshenkov Mikhail V.; Kaloshkin Sergey D.

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Calorimetric study of peculiar hydrogenation behavior of nanocrystalline TiFe

机译：纳米TiFe特殊氢化行为的量热研究

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摘要

Thermodynamic analysis of hydrogen interaction with TiFe nanocrystalline intermetallic compound produced by mechanical alloying has been carried out using microcalorimetric titration technique. The boundary of the phase regions and H-2 absorption/desorption reaction enthalpies have been defined in comparison with conventional as-cast alloy. It has been concluded that specific microstructure and oxygen contamination determine the system features within the a solid solution region and play a key role in formation of beta(2) and gamma, but does not affect the thermodynamic parameters of the main beta -> alpha transformation. (C) 2016 Elsevier B.V. All rights reserved.

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《Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics》 |2016年第1期|共5页
作者
Berdonosova Elena A.; Klyamkin Semen N.; Zadorozhnyy Vladislav Yu.; Zadorozhnyy Mikhail Yu.; Geodakian Karen V.; Gorshenkov Mikhail V.; Kaloshkin Sergey D.;
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正文语种 eng
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关键词
Mechanical alloying; Hydrogen storage; Intermetallic hydrides; Calorimetry;

机译：机械合金化;储氢;金属间氢化物;量热法;

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1. Calorimetric study of peculiar hydrogenation behavior of nanocrystalline TiFe [J] . Berdonosova Elena A., Klyamkin Semen N., Zadorozhnyy Vladislav Yu., Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2016,第Pta1期

机译：纳米TiFe特殊氢化行为的量热研究
2. Hydrogen storage nanocrystalline TiFe intermetallic compound: Synthesis by mechanical alloying and compacting [J] . V. Zadorozhnyy, S. Klyamkin, M. Zadorozhnyy, International journal of hydrogen energy . 2012,第22期

机译：储氢纳米晶TiFe金属间化合物：机械合金化和压制合成
3. Mechanochemical Synthesis and Hydrogen Sorption Properties of Nanocrystalline TiFe [J] . V. Yu. Zadorozhnyy, S. N. Klyamkin, S. D. Kaloshkin, Inorganic materials . 2011,第10期

机译：纳米晶TiFe的机械化学合成和吸氢性能
4. Comparative Study of Surface State and Electrochemical Properties of TiFe2V Hydrogen Storage as Well as TiFe-5 V Alloy by XPS and Polarization Curves Method [C] . T.N. Veziroglu Hydrogen Energy Progress XIII . 2000

机译：用XPS和极化曲线法研究TiFe2V储氢以及TiFe-5％V合金的表面态和电化学性质的比较。
5. Calorimetric studies of thermally induced phase separation of hydrogen-bonded polymer blends. [D] . Chiu, Shih-Chien. 2000

机译：氢键聚合物共混物热诱导相分离的量热研究。
6. A Calorimetric Study of the Glass Transition Behaviors in Axes of Bean Seeds with Relevance to Storage Stability. [O] . O. Leprince, C. Walters-Vertucci 1995

机译：量热法研究豆种子轴中的玻璃化转变行为与储存稳定性有关。
7. Preparation and hydrogen storage properties of nanocrystalline TiFe synthesized by mechanical alloying [O] . V.Yu. Zadorozhnyy, G.S. Milovzorov, S.N. Klyamkin, 2017

机译：机械合金化制备纳米晶TiFe的制备及储氢性能
8. NMR Studies of Hydrogen Relaxation and Diffusion in TiFeH/sub X/ and TiFe/sub 1-Y/Mn/sub Y/H/sub X/ [R] . Bowman, R. C., Carter, G. C., Chabre, Y., 1977

机译：TiFeH / sub X /和TiFe / sub 1-Y / mn / sub Y / H / sub X /的氢弛豫和扩散的NmR研究

Calorimetric study of peculiar hydrogenation behavior of nanocrystalline TiFe

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