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首页> 外文期刊>Journal of Materials Science >One pot synthesis of a highly water-dispersible hybrid glucose carbides and reduced graphene oxide material with superior electrical capacitance
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One pot synthesis of a highly water-dispersible hybrid glucose carbides and reduced graphene oxide material with superior electrical capacitance

机译:一锅合成高水分散性混合碳化碳化物和具有卓越电容量的还原氧化石墨烯材料

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In this paper, reduced graphene oxide with glucose carbides (RGO-GC) was synthesized in a simple one pot synthesis via a hydrothermal approach. Graphene oxide (GO) dispersion was dissolved together with glucose in water, and the mixture was heated to 180 C in an autoclave. After hydrothermal treatment, a thin GO-like glucose carbides (GC) film grows in situ on the RGO surface. Differing from RGO, the obtained RGO-GC not only has a much better dispersion in water, but also can be used as a support and a green reductant to fabricate Ag-decorated RGO-GC. Moreover, the maximum specific capacitance of the RGO-GC reaches as high as 247 F g~(-1) at a charging/discharging current density of 0.1 A g~(-1) in 1 M H_2SO_4 solution. After 1000 charging/discharging cycles, the specific capacitance still retains 95 % of its initial specific capacitance. The greatly improved electrochemical performance is attributed to the increased surface wettability, more effective ionic diffusion, and a higher conductivity arising from the hydrophilic GO-like GC grown on the RGO surfaces.
机译:在本文中,通过水热法以简单的一锅法合成了具有碳化葡萄糖的还原氧化石墨烯(RGO-GC)。将氧化石墨烯(GO)分散体与葡萄糖一起溶解在水中,并将混合物在高压釜中加热至180℃。经过水热处理后,RGO表面上会原位生长一个薄的GO状碳化碳化物(GC)薄膜。与RGO不同,所获得的RGO-GC不仅在水中具有更好的分散性,而且可以用作载体和绿色还原剂以制备Ag修饰的RGO-GC。此外,在1 M H_2SO_4溶液中,在0.1 A g〜(-1)的充放电电流密度下,RGO-GC的最大比电容高达247 F g〜(-1)。经过1000次充电/放电循环后,比电容仍保留其初始比电容的95%。电化学性能的极大改善归因于RGO表面上生长的亲水性类GO气相色谱的增加的表面润湿性,更有效的离子扩散和更高的电导率。

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