Structure and vibrational spectra of M-3VI(IIAIVB)-type crystalline and glassy semiconductors

Bletskan DI.; Kabacij VN.; Sakal TA.; Stefanovych VA.

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Structure and vibrational spectra of M-3VI(IIAIVB)-type crystalline and glassy semiconductors

机译：M-3VI（IIAIVB）型晶体和玻璃态半导体的结构和振动光谱

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The crystal structure PbGeS3 and SnGeS3 compounds consists of infinite chains of top-sharing [GeS4] tetrahedra. These chains are 'laced' together by chains of psi-octahedra coordinating the lead (tin) atoms. The vibrational spectra of ordered and disordered phases of PbGeS3 and SnGeS3 in the range of symmetric vibration A(1) were studied taking into account the crystalline structure. The factors determining the peculiarities of the vibrational spectrum have been discussed. The role of the [GeS4] tetrahedra as universal structural units in the formation of the vibrational spectra of crystalline and glassy tin and lead thiogermanates is noted. On the basis of the similarity of vibrational spectra it was concluded that the glasses in Ge2S3-SnGeS3-PbGeS3 series are isostructural. (C) 2003 Elsevier B.V. All rights reserved. [References: 12]

机译：PbGeS3和SnGeS3化合物的晶体结构由顶部共享[GeS4]四面体的无限链组成。这些链通过psi-八面体链与铅（锡）原子“系结”在一起。考虑到晶体结构，研究了对称振动A（1）范围内PbGeS3和SnGeS3有序和无序相的振动谱。讨论了确定振动频谱特性的因素。注意到[GeS4]四面体作为通用结构单元在结晶和玻璃态锡和硫代锗酸铅的振动光谱中的作用。根据振动光谱的相似性，得出Ge2S3-SnGeS3-PbGeS3系列玻璃是同构的。（C）2003 Elsevier B.V.保留所有权利。 [参考：12]

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《Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites》 |2003年第0期|共6页
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Bletskan DI.; Kabacij VN.; Sakal TA.; Stefanovych VA.;
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Chalcogenide systems; Phase-diagram;

机译：硫属化物系统;相图;

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1. Structure and vibrational spectra of M-3VI(IIAIVB)-type crystalline and glassy semiconductors [J] . Bletskan DI., Kabacij VN., Sakal TA., Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites . 2003,第0期

机译：M-3VI（IIAIVB）型晶体和玻璃态半导体的结构和振动光谱
2. Dependence of vibrational density of states and Raman spectra on size in non-polar and polar nano-crystalline semiconductors [J] . Liu W, Liu MX, Zhang SL Physics Letters, A . 2008,第14期

机译：非极性和极性纳米晶体半导体中态振动密度和拉曼光谱对尺寸的依赖性
3. Dependence of vibrational density of states and Raman spectra on size in non-polar and polar nano-crystalline semiconductors [J] . Liu W, Liu MX, Zhang SL Physics Letters, A . 2008,第14期

机译：非极性和极性纳米晶体半导体中态振动密度和拉曼光谱对尺寸的依赖性
4. Raman Spectra and Structure of Silicon—Oxygen Groups in Crystalline, Molten, and Glassy Mg_2SiO_4 [C] . V. E. Shukshin, Yu. K. Voronko, A. A. Sobol International Conference on Raman Spectroscopy . 2010

机译：结晶，熔化和玻璃型Mg_2sio_4中拉曼光谱和硅 - 氧基团的结构
5. A multinuclear NMR study of hydrous aluminosilicate glasses: Crystalline versus glassy structures. [D] . Oglesby, Jane Virginia. 2001

机译：含水硅铝酸盐玻璃的多核NMR研究：晶体结构与玻璃结构。
6. Universal phonon mean free path spectra in crystalline semiconductors at high temperature [O] . Justin P. Freedman, Jacob H. Leach, Edward A. Preble, -1

机译：高温下晶体半导体中的通用声子平均自由程谱
7. Structure and vibrational spectra of -hydroxy isobutyric acid in the crystalline and glassy phases and isolated in inert gas matrixes [O] . Jarmelo Susana, Fausto Rui 2002

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8. Structural Correlations and Vibrational Spectra of Molten and Glassy GeSe2. [R] . Vashishta, P., Kalia, R. K., Ebbsjoe, I. 1988

机译：熔融和玻璃Gese2的结构相关性和振动光谱。

Structure and vibrational spectra of M-3VI(IIAIVB)-type crystalline and glassy semiconductors

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