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The effect of inter-cluster interactions on the structure of colloidal clusters

机译:簇间相互作用对胶体簇结构的影响

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摘要

Colloidal systems present exciting opportunities to study clusters. Unlike atomic clusters, which are frequently produced at extremely low density, colloidal clusters may interact with one another. Here we consider the effect of such interactions on the intra-cluster structure in simulations of colloidal cluster fluids. A sufficient increase in density leads to a higher population of clusters in the ground state. In other words, inter-cluster interactions perturb the intra-cluster behaviour, such that each cluster may no longer be considered as an isolated system. Conversely, for dilute, weakly interacting cluster fluids little dependence on colloid concentration is observed, and we thus argue that it is reasonable to treat each cluster as an isolated system.
机译:胶体系统为研究团簇提供了令人兴奋的机会。与通常以极低的密度产生的原子团簇不同,胶体团簇可能彼此相互作用。在这里,我们在胶体团簇流体的模拟中考虑了这种相互作用对团簇内结构的影响。密度的充分增加导致基态中簇的数量增加。换句话说,集群间的交互干扰了集群内的行为,因此每个集群都不再被视为一个孤立的系统。相反,对于稀疏,弱相互作用的团簇流体,几乎没有观察到对胶体浓度的依赖性,因此我们认为将每个团簇视为一个独立的系统是合理的。

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