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Effect of free electron concentration on glass-forming ability of Ca-Mg-Cu system

机译:自由电子浓度对Ca-Mg-Cu体系玻璃形成能力的影响

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摘要

Intensive studies show that the best glass-forming ability (GFA) is presented as the Fermi surface made contact with pseudo-Brillouin boundaries. Via surveying the GFA of electronic simple Ca-Mg-Cu metallic glass system, we find that the best GFA is presented as the free electrons per atom (e/a) equals to 1.75, which is closed to the value of 1.8 proposed for the ideal amorphous state. The pseudo-gap or minimum in the density of states at the Fermi surface proposed by nearly free electron theory has not been observed in the Ca-Mg-Cu system. Our results indicate that the free electron concentration is an important but not the sole factor for influences in the glass formation.
机译:深入的研究表明,当费米表面与伪布里渊边界接触时,呈现出最佳的玻璃形成能力(GFA)。通过调查简单的Ca-Mg-Cu电子玻璃系统的GFA,我们发现最佳GFA表示为每个原子的自由电子(e / a)等于1.75,接近于建议的1.8值。理想的非晶态。在Ca-Mg-Cu系统中,未观察到由几乎自由电子理论提出的费米表面上的伪间隙或最小状态密度。我们的结果表明,自由电子浓度是影响玻璃形成的重要而不是唯一的因素。

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