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Determination of the complete metastable liquid miscibility gap in Pd-Ni-P

机译:Pd-Ni-P中完全亚稳态液体混溶间隙的确定

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摘要

Despite having a negative heat of mixing, a metastable liquid/amorphous miscibility gap (MLMG) was found below the liquidus of the alloy system, Pd-Ni-P. Earlier, a direct determination of the complete MLMG was not possible because it lies in the undercooling regime. It is known that the morphology of an alloy system that has undergone a spinodal mechanism is interconnected. In this work, a morphological transition, from eutectic to interconnectedness, was used to determine the complete MLMG of the alloy system, Pd-Ni-P. (C) 2015 Elsevier B.V. All rights reserved.
机译:尽管有负的混合热,但在合金体系Pd-Ni-P的液相线下方发现了亚稳态的液体/非晶态混溶间隙(MLMG)。早先,不可能直接确定完整的MLMG,因为它处于过冷状态。众所周知,经历了旋节线机制的合金系统的形态是相互关联的。在这项工作中,从共晶到互连的形态转变被用于确定合金体系Pd-Ni-P的完整MLMG。 (C)2015 Elsevier B.V.保留所有权利。

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